Bis[1,2-bis(diphenylphosphino)ethane-P,P'] chloroosmium(II) hexafluorophosphate dichloromethane solvate

被引：2
|
作者：
Lough, AJ
Morris, RH
Schlaf, M
机构：
[1] Department of Chemistry, University of Toronto, Toronto
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1996年 / 52卷
关键词：
D O I：
10.1107/S0108270196006208
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The cation molecule of the title compound, [OsCl(C26H24P2)(2)]PF6.1.5CH(2)Cl(2), has a distorted trigonal-bipyramidal structure. Despite strong steric repulsion between the PPh(2) groups, the Os-P bonds in the equatorial plane are short [2.2416(12) and 2.2587(13) Angstrom] and the P-Os-P angle is only 94.24(5)degrees.
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收藏
页码：2193 / 2196
页数：4
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