Bis[1,2-bis(diphenylphosphino)ethane-P,P'] chloroosmium(II) hexafluorophosphate dichloromethane solvate

被引：2

作者：

Lough, AJ

Morris, RH

Schlaf, M

机构：

[1] Department of Chemistry, University of Toronto, Toronto

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196006208

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cation molecule of the title compound, [OsCl(C26H24P2)(2)]PF6.1.5CH(2)Cl(2), has a distorted trigonal-bipyramidal structure. Despite strong steric repulsion between the PPh(2) groups, the Os-P bonds in the equatorial plane are short [2.2416(12) and 2.2587(13) Angstrom] and the P-Os-P angle is only 94.24(5)degrees.

引用

页码：2193 / 2196

页数：4

共 13 条

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