Recent advances in oxygen electrocatalysts based on tunable structural polymers

被引：52

作者：

Gopalakrishnan, M. ^{[1
]}

Mohamad, A. A. ^{[2
]}

Nguyen, M. T. ^{[3
]}

Yonezawa, T. ^{[3
,4
]}

Qin, J. ^{[5
,6
]}

Thamyongkit, P. ^{[7
]}

Somwangthanaroj, A. ^{[1
,8
]}

Kheawhom, S. ^{[1
,6
,8
]}

机构：

[1] Chulalongkorn Univ, Fac Engn, Dept Chem Engn, Bangkok 10330, Thailand

[2] Univ Sains Malaysia, Sch Mat & Mineral Resources Engn, Nibong Tebal 14300, Malaysia

[3] Hokkaido Univ, Fac Engn, Div Mat Sci & Engn, Sapporo, Hokkaido 0608628, Japan

[4] Hokkaido Univ, Inst Promot Business Reg Collaborat, Sapporo, Hokkaido 0010021, Japan

[5] Chulalongkorn Univ, Met & Mat Sci Res Inst, Bangkok 10330, Thailand

[6] Chulalongkorn Univ, Res Unit Adv Mat Energy Storage, Bangkok 10330, Thailand

[7] Chulalongkorn Univ, Fac Sci, Dept Chem, Bangkok 10330, Thailand

[8] Chulalongkorn Univ, Fac Engn, BioCircular Green Econ Technol & Engn Ctr BCGeTEC, Bangkok 10330, Thailand

来源：

MATERIALS TODAY CHEMISTRY | 2022年 / 23卷

基金：

日本科学技术振兴机构;

关键词：

Covalent organic polymer; Metal coordination polymer; Pyrolysis-free polymer; Costs; Zinc-air battery; METAL-ORGANIC FRAMEWORKS; ZINC-AIR BATTERIES; MULTIWALLED CARBON NANOTUBES; REDUCTION REACTION; WATER OXIDATION; EFFICIENT ELECTROCATALYSTS; RATIONAL DESIGN; DOPED GRAPHENE; CATALYSTS; ORR;

D O I：

10.1016/j.mtchem.2021.100632

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Due to their high energy density, great safety and eco-friendliness, zinc-air batteries (ZABs) attract much attention. During the process of charging and discharging, the two key processes viz. oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) limit their efficiency. In general, the noble metal-based electrocatalysts (ORR: platinum (Pt); OER: iridium (IV) oxide [IrO2] and ruthenium oxide [RuO2]) have long been used. Nonetheless, these noble metal electrocatalysts also have their limitations owing to high cost and poor stability. As alternatives, polymers are found to be most promising on account of their tunable structure, uniform network, high surface morphology and strong durability. Polymers are capable catalysts. In this review, recent advances as well as insight into the architecture of covalent organic polymers (COPs), metal coordination polymers (MCPs) and pyrolysis-free polymers (PFPs) are duly outlined. (C) 2021 The Author(s). Published by Elsevier Ltd.

引用

页数：22

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