Stable N-Heterocyclic Carbene Complexes of Hypermetallyl Germanium(II) and Tin(II) Compounds

被引：60
|
作者：
Katir, Nadia [1 ,2 ]
Matioszek, Dimitri [1 ,2 ]
Ladeira, Sonia [3 ]
Escudie, Jean [1 ,2 ]
Castel, Annie [1 ,2 ]
机构：
[1] Univ Toulouse, UPS, LHFA, F-31062 Toulouse, France
[2] CNRS, LHFA UMR 5069, F-31062 Toulouse, France
[3] Struct Federat Toulousaine Chim Mol, F-31062 Toulouse, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 23期
关键词：
carbene homologues; carbene ligands; germanium; hypermetallyl ligands; tin; STANNYLENE ADDUCT; DOUBLE-BOND; CHEMISTRY; SILICON; TIN; NANOWIRES; HOMOLOGS; NANOCRYSTALS; DERIVATIVES; GERMYLENES;
D O I：
10.1002/anie.201100634
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A selective route: Hypermetallyl germanium(II) and tin(II) compounds (see scheme) were prepared using dimetallyl magnesium reagents and were fully characterized. These derivatives, which contain good leaving substituents, might be suitable candidates for the preparation of nanomaterial alloys. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：5352 / 5355
页数：4
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