Unprecedented carbon-carbon bond formation induced by photoactivation of a platinum(IV)-diazido complex

被引：40

作者：

Ronconi, Luca ^{[1
]}

Sadler, Peter J. ^{[1
,2
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 02期

关键词：

D O I：

10.1039/b714216a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

UVA-induced photodecomposition of a Pt-IV-diazido complex involves not only reduction to Pt-II and N-2 release, but also O-2 evolution and formation of nitrene intermediates, whose trapping with (CH3)(2)S gives rise to an unusual N,N'-bis(ethyl)-sulfurousdiamide ligand in an apparently unprecedented process involving C-C bond formation.

引用

页码：235 / 237

页数：3

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