Standard enthalpy of formation of (ClOF2)2[NiF6](cryst.)

被引：2

作者：

Solov'ev, S. N. ^{[1
]}

Shatalov, K. I. ^{[1
]}

Dupal, A. Ya. ^{[1
]}

机构：

[1] Mendeleyev Univ Chem Technol Russia, Moscow 125047, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2011年 / 85卷 / 10期

关键词：

calorimeter; enthalpy of reaction; aqueous solutions; alkali; enthalpy of formation; (ClOF2)(2)[NiF6;

D O I：

10.1134/S0036024411100268

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The enthalpies of reaction between crystalline (ClOF2)(2)[NiF6] and water and an aqueous solution of alkali are measured at 298.15 K using a highly sensitive isothermal shell calorimeter. On the basis of these values and the published data, the standard enthalpy of formation of the studied compound is found by two independent methods; its value is Delta (f) H-o(ClOF2)(2)[NiF6]](cryst.) = -1158 +/- 11 kJ/mol.

引用

页码：1855 / 1856

页数：2