The interaction of nickelocene with 3,6-di-tert-butyl-o-benzoquinone

被引：10

作者：

Piskunov, AV ^{[1
]}

Fukin, GK ^{[1
]}

Kurskii, YA ^{[1
]}

Cherkasov, VK ^{[1
]}

Abakumov, GA ^{[1
]}

机构：

[1] RAS, GA Razuvaev Inst Organomet Chem, Nizhnii Novgorod 603950, Russia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

nickelocene; o-quinone; pi-allyl complex; o-semiquinone; X-ray diffraction;

D O I：

10.1016/j.inoche.2005.01.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The interaction of nickelocene with 3,6-di-tert-butyl-o-benzoquinone in toluene gives new 18-electron complex (eta(5)-cyclopentadienyl)(eta(3)-{5,8-di-tert-butyl-3a,9a-dihydro-1H-cyclopenta(b)[1,4]benzodioxin-1-il})nickel(II) as the main product of hetero-Diels-Alder reaction. This process being carried out in THF solution is accompanied by ligands exchange and leads mainly to octahedral complex bis(3,6-di-tert-butyl-o-benzosemiquinonate)-bis(tetrahydrofuran)nickel(II). (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：339 / 342

页数：4

共 40 条

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