The interaction of nickelocene with 3,6-di-tert-butyl-o-benzoquinone

被引：10
|
作者：
Piskunov, AV [1 ]
Fukin, GK [1 ]
Kurskii, YA [1 ]
Cherkasov, VK [1 ]
Abakumov, GA [1 ]
机构：
[1] RAS, GA Razuvaev Inst Organomet Chem, Nizhnii Novgorod 603950, Russia
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 04期
基金：
俄罗斯基础研究基金会;
关键词：
nickelocene; o-quinone; pi-allyl complex; o-semiquinone; X-ray diffraction;
D O I：
10.1016/j.inoche.2005.01.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The interaction of nickelocene with 3,6-di-tert-butyl-o-benzoquinone in toluene gives new 18-electron complex (eta(5)-cyclopentadienyl)(eta(3)-{5,8-di-tert-butyl-3a,9a-dihydro-1H-cyclopenta(b)[1,4]benzodioxin-1-il})nickel(II) as the main product of hetero-Diels-Alder reaction. This process being carried out in THF solution is accompanied by ligands exchange and leads mainly to octahedral complex bis(3,6-di-tert-butyl-o-benzosemiquinonate)-bis(tetrahydrofuran)nickel(II). (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：339 / 342
页数：4
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