Two-Photon Lithography of Sub-Wavelength Metallic Structures in a Polymer Matrix

被引:67
作者
Shukla, Shobha [2 ]
Furlani, Edward P.
Vidal, Xavier
Swihart, Mark T. [3 ]
Prasad, Paras N. [1 ]
机构
[1] SUNY Buffalo, Inst Lasers Photon & Biophoton, Buffalo, NY 14260 USA
[2] SUNY Buffalo, Dept Elect Engn, Inst Lasers Photon & Biophoton, Buffalo, NY 14260 USA
[3] SUNY Buffalo, Dept Chem Engn, Inst Lasers Photon & Biophoton, Buffalo, NY 14260 USA
关键词
OPTICAL-DATA STORAGE; DIFFRACTION LIMIT; MICROSTRUCTURES; PHOTOREDUCTION; MICROFABRICATION; METAMATERIALS; NANOPARTICLES; PHOTON;
D O I
10.1002/adma.201000059
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel method for fabricating metallic nanostructures with sub-wavelength resolution in a polymer using simultaneous two-photon initiated reduction of a metal salt and polymerization of a negative photoresist is demonstrated. Gold nanoparticle-doped lines as narrow as 200 nm are fabricated. The dependence of line-width on laser intensity and scan speed are captured well by an analytical model. We create functional gratings and planar chiral elements, characterize their optical properties, and model their electromagnetic response.
引用
收藏
页码:3695 / +
页数:6
相关论文
共 29 条
[1]   Optical activity in planar chiral metamaterials: Theoretical study [J].
Bai, Benfeng ;
Svirko, Yuri ;
Turunen, Jari ;
Vallius, Tuomas .
PHYSICAL REVIEW A, 2007, 76 (02)
[2]   Multiphoton laser direct writing of two-dimensional silver structures [J].
Baldacchini, T ;
Pons, AC ;
Pons, J ;
LaFratta, CN ;
Fourkas, JT ;
Sun, Y ;
Naughton, MJ .
OPTICS EXPRESS, 2005, 13 (04) :1275-1280
[3]   Beat the diffraction limit in 3D direct laser writing in photosensitive glass [J].
Bellec, Matthieu ;
Royon, Arnaud ;
Bousquet, Bruno ;
Bourhis, Kevin ;
Treguer, Mona ;
Cardinal, Thierry ;
Richardson, Martin ;
Canioni, Lionel .
OPTICS EXPRESS, 2009, 17 (12) :10304-10318
[4]   A metal-wire/quantum-dot composite metamaterial with negative ε and compensated optical loss [J].
Bratkovsky, Alexander ;
Ponizovskaya, Ekaterina ;
Wang, Shih-Yuan ;
Holmstrom, Petter ;
Thylen, Lars ;
Fu, Ying ;
Agren, Hans .
APPLIED PHYSICS LETTERS, 2008, 93 (19)
[5]   Morphology and size dependence of silver microstructures in fatty salts-assisted multiphoton photoreduction microfabrication [J].
Cao, Yao-Yu ;
Dong, Xian-Zi ;
Takeyasu, Nobuyuki ;
Tanaka, Takuo ;
Zhao, Zhen-Sheng ;
Duan, Xuan-Ming ;
Kawata, Satoshi .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2009, 96 (02) :453-458
[6]   Suspension of nanoparticles in SU-8: Processing and characterization of nanocomposite polymers [J].
Chiamori, H. C. ;
Brown, J. W. ;
Adhiprakasha, E. V. ;
Hantsoo, E. T. ;
Straalsund, J. B. ;
Melosh, N. A. ;
Pruitt, B. L. .
MICROELECTRONICS JOURNAL, 2008, 39 (02) :228-236
[7]   Molecular mechanism of the photochemical generation of gold nanoparticles in ethylene glycol: Support for the disproportionation mechanism [J].
Eustis, Susie ;
El-Sayed, Mostafa A. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (29) :14014-14019
[8]   Femtosecond laser micromachining in transparent materials [J].
Gattass, Rafael R. ;
Mazur, Eric .
NATURE PHOTONICS, 2008, 2 (04) :219-225
[9]   Log-pile photonic crystal fabricated by two-photon photopolymerization [J].
Guo, R ;
Li, ZY ;
Jiang, ZW ;
Yuan, DJ ;
Huang, WH ;
Xia, AD .
JOURNAL OF OPTICS A-PURE AND APPLIED OPTICS, 2005, 7 (08) :396-399
[10]   Multiscale patterning of plasmonic metamaterials [J].
Henzie, Joel ;
Lee, Min Hyung ;
Odom, Teri W. .
NATURE NANOTECHNOLOGY, 2007, 2 (09) :549-554