[Ni(C10H8N2)3]2[V4O12].11H2O

被引：28
|
作者：
Yang, GY [1 ]
Gao, DW
Chen, Y
Xu, JQ
Zeng, QX
Sun, HR
Pei, ZW
Su, Q
Xing, Y
Ling, YH
Jia, HQ
机构：
[1] Jilin Univ, Dept Chem, Changchun 130023, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Appl Chem, Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1998年 / 54卷
关键词：
D O I：
10.1107/S0108270197018751
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structure of the title compound, bis[tris(2,2'-bipyridyl-N,N')nickel(II)] cyclo-tetravanadate undecahydrate, contains a centrosymmetric [V4O12](4-) anion, which has an eight-membered ring structure formed by four VO4 tetrahedra sharing vertices, and two complex cations containing octahedrally-coordinated Ni-II ions. The anion and coordinated Ni-II ions are isolated and make up anion and cation layers, respectively. The Ni-N distances range from 2.077(3) to 2.112(2)Angstrom and the V-O distances range from 1.621(2) to 1.803(2)Angstrom.
引用
收藏
页码：616 / 618
页数：3
相关论文
共 50 条
  • [41] Two new soluble iron-oxo complexes:: [Fe2(μ-O)(μ-O2CCF3)2(O2CCF3)2-(C10H8N2)2] and [Fe4(μ3-O)2(μO2CCF3)6(O2CCF3)2(C10H8N2)2]•CF3CO2H
    Bacsa, J
    Zhao, HH
    Dunbar, KR
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2003, 59 : M561 - M564
  • [42] Crystal structure of diaqua(4,4′-bipyridine-N,N′)-bis(2-benzoylbenzoato)-cadmium(II) dihydrate, Cd(C14H9O3)2(C10H8N2)(H2O)2 • 2H2O
    Chen, Zhi-Min
    Yang, Ying-Qun
    Zou, Jian-Ling
    Kuang, Dai-Zhi
    Zhang, Fu-Xing
    Wang, Jian-Qiu
    Chen, Man-Sheng
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2011, 226 (03): : 337 - 338
  • [43] Crystal structure of tetraaqua(4,4′-bipyridine-N,N′)copper(II) fumarate tetrahydrate, Cu(H2O)4(C10H8N2)(C4H2O4)•4H2O
    Ying, EB
    Zheng, YQ
    Zhou, QQ
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2004, 219 (01): : 65 - 66
  • [44] Crystal structure of 4,4′-bipyridinium bis(hydrogen 3,5-pyrazoledicarboxylate) tetrahydrate, [C5H4N2O4]2[C10H8N2] • 4H2O
    Li, Xiu-Ying
    Liu, Ling
    Wang, Shan-Shan
    Wang, Miao-Miao
    Che, Guang-Bo
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2012, 227 (01): : 73 - 74
  • [45] Crystal structure of triaqua-(2,2′-bipyridine)-(5-nitroisophthalato)nickel(II) monohydrate, Ni(H2O)3(C10H8N2)(C8H3NO6) • H2O
    Zhao, Ning
    Lian, Zhaoxun
    Deng, Yue'e
    Gu, Yongqing
    Li, Xiaobo
    Zhang, Jiamin
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2009, 224 (02): : 323 - 324
  • [46] 杂多酸盐[(C10H10N2)(C10H9N2)(PMo12O40)]·(C10H8N2)2·7H2O的水热合成及其结构研究
    杨颖群
    陈志敏
    李薇
    邓戊有
    邹建陵
    衡阳师范学院学报, 2009, 30 (03) : 70 - 73
  • [47] Crystal structure of catena-diaqua(N-p-acetamidobenzene-sulfonylglycinato)holmium(III) 4,4′-bipyridine heptahydrate, [Ho(C10H11N2O5S)3(H2O)2] • C10H8N2 • 7H2O
    Qin, Jian-Hua
    Wang, Jian-Ge
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2009, 224 (01): : 44 - 46
  • [48] Crystal Structures of Na3PO2S2 · 11H2O and Na3POS3 · 11H2O
    Markus Pompetzki
    Martin Jansen
    Monatshefte für Chemie / Chemical Monthly, 2002, 133 : 975 - 986
  • [49] Unique seven-node rare-earth octacyanomolybdate(IV) three-dimensional molecular frameworks: {[Er(H2O)5(Er(H2O)4)3][Mo(CN)8]3•11H2O}n and {[Eu(H2O)5(Eu(H2O)4)3][Mo(CN)8]3•11H2O}n
    Semenyshyn, Dariya
    Typilo, Iryna
    Sereda, Olha
    Dolomanov, Oleg
    Stoeckli-Evans, Helen
    SOLID STATE SCIENCES, 2012, 14 (09) : 1321 - 1326
  • [50] Synthesis, structure and characterization of three different dimension inorganic-organic hybrid vanadates: [Co2(mIM)5(H2O)2]V4O12,[Ni2(mIM)7(H2O)]V4O12•H2O and [Cd(eIM)2(H2O)]V2O6
    Wu, Shujun
    Yang, Xinhang
    Hu, Jufang
    Ma, Hongwei
    Lin, Zhengguo
    Hu, Changwen
    CRYSTENGCOMM, 2015, 17 (07) : 1625 - 1630
12345