Modelling of crystal growth of KDP in a 100 dm3 suspension crystallizer using combination of CFD and multiblock model

被引:12
作者
Liiri, Maret [1 ]
Hatakka, Henry [2 ]
Kallas, Juha [2 ]
Aittamaa, Juhani [3 ]
Alopaeus, Ville [1 ]
机构
[1] Aalto Univ, Sch Sci & Technol, Dept Biotechnol & Chem Technol, Espoo 00076, Finland
[2] Lappeenranta Univ Technol, Dept Chem Technol, Lappeenranta 53851, Finland
[3] Neste Jacobs Oy, Porvoo 06101, Finland
基金
芬兰科学院;
关键词
Modelling; Crystal growth; Multiblock model; CFD; POTASSIUM DIHYDROGEN PHOSPHATE; NONIDEAL STIRRED-TANK; LIQUID-LIQUID SYSTEMS; INDUSTRIAL CRYSTALLIZERS; POPULATION BALANCES; SIMULATION; VALIDATION;
D O I
10.1016/j.cherd.2009.12.004
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In this study a combination of computational fluid dynamics (CFD) and multiblock model is used for modelling crystal growth in a 100 dm(3) suspension crystallizer equipped with two turbine impellers. Local hydrodynamics and crystal suspension densities were modelled using CFD. Simulation results were compared with experimental results to verify flow profile and slip velocities (Hatakka et al., 2008, 2009), and classification of crystals. Results from CFD simulations were then translated to a proper form and used as input data for the multiblock model. The same multiblock model has previously been used successfully for modelling gas-liquid systems (Laakkonen, 2006). For this study a growth model for potassium dihydrogen phosphate (KDP) was imported into the multiblock model. We used the power-law growth model including activity-based driving force. The growth model was developed based on single crystal experiments of KDP (Liiri et al., 2006). Growth of KDP crystals in the 100 dm3 suspension crystallizer was simulated with the multiblock model. Verification was done by comparing the simulated results with results from crystal growth experiments. (C) 2009 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:1297 / 1303
页数:7
相关论文
共 19 条
[1]   Simulation of the population balances for liquid-liquid systems in a nonideal stirred tank. Part 2 - parameter fitting and the use of the multiblock model for dense dispersions [J].
Alopaeus, V ;
Koskinen, J ;
Keskinen, KI ;
Majander, J .
CHEMICAL ENGINEERING SCIENCE, 2002, 57 (10) :1815-1825
[2]   Simulation of the population balances for liquid-liquid systems in a nonideal stirred tank. Part 1 Description and qualitative validation of the model [J].
Alopaeus, V ;
Koskinen, J ;
Keskinen, KI .
CHEMICAL ENGINEERING SCIENCE, 1999, 54 (24) :5887-5899
[3]   Towards on-scale crystalliser design using compartmental models [J].
Bermingham, SK ;
Kramer, HJM ;
van Rosmalen, GM .
COMPUTERS & CHEMICAL ENGINEERING, 1998, 22 :S355-S362
[4]   INVESTIGATION OF MICROMIXING IN STIRRED-TANK REACTORS USING PARALLEL REACTIONS [J].
BOURNE, JR ;
YU, SY .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1994, 33 (01) :41-55
[5]  
HATAKKA H, 2009, P ISIC17 MAASTR NETH, P1851
[6]  
Him SJ, 1996, IND ENG CHEM RES, V35, P1078
[7]   Modeling of industrial crystallizers for control and design purposes [J].
Kramer, HJM ;
Dijkstra, JW ;
Verheijen, PJT ;
Van Rosmalen, GM .
POWDER TECHNOLOGY, 2000, 108 (2-3) :185-191
[8]   Modelling of industrial crystallizers, a compartmental approach using a dynamic flow-sheeting tool [J].
Kramer, HJM ;
Dijkstra, JW ;
Neumann, AM ;
Meadhra, RO ;
vanRosmalen, GM .
JOURNAL OF CRYSTAL GROWTH, 1996, 166 (1-4) :1084-1088
[9]   A framework for the simulation of mass crystallization considering the effect of fluid dynamics [J].
Kulikov, Viatcheslav ;
Briesen, Heiko ;
Marquardt, Wolfgang .
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2006, 45 (10) :886-899
[10]   Validation of bubble breakage, coalescence and mass transfer models for gas-liquid dispersion in agitated vessel [J].
Laakkonen, M ;
Alopaeus, V ;
Aittamaa, J .
CHEMICAL ENGINEERING SCIENCE, 2006, 61 (01) :218-228