The carbonylation reaction of nitrobenzene to methyl phenylcarbamate: Highly efficient promoters for the palladium-phenanthroline catalytic system based on phosphorus acids

被引：51
|
作者：
Ragaini, F
Cognolato, C
Gasperini, M
Cenini, S
机构：
[1] CNR, Dipartimento Chim Inorgan Met Organ & Analit, ISTM, I-20133 Milan, Italy
[2] INSTM, UdR Milano, I-20133 Milan, Italy
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 25期
关键词：
carbamates; carbonylation; homogeneous catalysis; nitroarenes; palladium;
D O I：
10.1002/anie.200351004
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Phenomenal! The activity of the palladium-phenanthroline catalytic system for the carbonylation of nitrobenzene to methyl phenylcarbamate is greatly enhanced by the addition of phosphorus acids. Of those that were studied, the best promoter is the very cheap, easily separable, and nontoxic phosphoric acid.
引用
收藏
页码：2886 / 2889
页数：4
相关论文
共 7 条
1