Preparation and characterization of some cobalt(III) complexes of 2-aminomethylbenzimidazole

被引：13

作者：

Gable, RW ^{[1
]}

Hartshorn, RM ^{[1
]}

McFadyen, WD ^{[1
]}

Nunno, L ^{[1
]}

机构：

[1] UNIV MELBOURNE,SCH CHEM,PARKVILLE,VIC 3052,AUSTRALIA

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1996年 / 49卷 / 05期

关键词：

D O I：

10.1071/CH9960625

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination chemistry of 2-aminomethylbenzimidazole (ambi) has been studied with cobalt(III), and the cationic complexes fac-[Co(ambi)(3)](3+), asym-[Co(en)(ambi)(2)](3+) and [Co(en)(2)(ambi)](3+) have been prepared. The last cation, in the form of the chloride salt [Co(en)(2)(ambi)] Cl-3.H2O, has been structurally characterized: monoclinic, space group P2(1)/c, a 7 . 6692(14), b 14 . 954(2), c 15 . 941(3) Angstrom,beta 92 . 64(2)degrees, Z 4.

引用

页码：625 / 632

页数：8

共 14 条

[1] VAN DER WAALS VOLUMES + RADII [J].