Photoresponsive rolling and bending of thin crystals of chiral diarylethenes

被引:128
作者
Uchida, Kingo [1 ,2 ]
Sukata, Shin-ichiro [1 ]
Matsuzawa, Yuji [1 ]
Akazawa, Masako [1 ]
de Jong, Jaap J. D. [2 ]
Katsonis, Nathalie [2 ]
Kojima, Yuko [3 ,4 ]
Nakamura, Shinichiro [3 ,4 ]
Areephong, Jetsuda [2 ]
Meetsma, Auke [2 ]
Feringa, Ben L. [2 ]
机构
[1] Ryukoku Univ, Fac Sci & Technol, Dept Chem Mat, CREST JST, Shiga 5202194, Japan
[2] Univ Groningen, Stratingh Inst Chem, NL-9747 AG Groningen, Netherlands
[3] Japan Sci & Technol Corp, Sci & Technol Res Ctr Inc, Mitsubishi Chem Grp, Yokohama, Kanagawa 2278502, Japan
[4] Japan Sci & Technol Corp, CREST JST, Yokohama, Kanagawa 2278502, Japan
关键词
D O I
10.1039/b715251e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Dithienylhexafluorocyclopentene with (R)- or (S)-N-phenylethylamide substituents formed rod-like and 0.2-1.0 mu m-thick plate-like crystals by sublimation; upon UV irradiation, the crystals bent concavely to the incident light and finally rolled crystals were obtained; the bent crystals were reconverted to flat crystals by visible light irradiation.
引用
收藏
页码:326 / 328
页数:3
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