Gel-type ion exchange resin stabilized Pd-Bi nanoparticles for the glycerol oxidation in liquid phase

被引：23

作者：

Vajicek, Stanislav ^{[1
]}

Stolcova, Magdalena ^{[1
]}

Kaszonyi, Alexander ^{[1
]}

Micusik, Matej ^{[2
]}

Alexy, Pavel ^{[3
]}

Canton, Patrizia ^{[4
]}

Onyestyak, Gyorgy ^{[5
]}

Harnos, Szabolcs ^{[5
]}

Lonyi, Ferenc ^{[5
]}

Valyon, Jozsef ^{[5
]}

机构：

[1] Slovak Univ Technol Bratislava, Dept Organ Technol, Joint Slovak Hungarian Lab Dev Catalyzed Chem Pro, Radlinskeho 9, Bratislava 81237, Slovakia

[2] Slovak Acad Sci, Inst Polymer, Dubravska Cesta 9, Bratislava 84541, Slovakia

[3] Slovak Univ Technol Bratislava, Dept Plast & Rubber, Radlinskeho 9, Bratislava 81237, Slovakia

[4] Univ Venezia, Dipartimento Chim Fis, Via Torino 155-b, I-30170 Venice, Italy

[5] Ctr Nat Sci, Inst Mat & Res, Joint Slovak Hungarian Lab Dev Catalyzed Chem Pro, Magyar Tudosok Korutja 2, H-1117 Budapest, Hungary

来源：

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2016年 / 39卷

关键词：

Gel-type anion-exchange resin; Pd-Bi nanoparticles; Glycerol liquid-phase oxidation; Glyceric acid; Tartronic acid; SELECTIVE CATALYTIC-OXIDATION; FREE AQUEOUS-SOLUTION; ALCOHOL OXIDATION; AEROBIC OXIDATION; GOLD; AU; BISMUTH; PLATINUM; CARBON; AIR;

D O I：

10.1016/j.jiec.2016.05.010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium-bismuth nanoparticles were supported into strongly basic anion-exchange resin of gel-type and tested as catalysts for the selective oxidation of glycerol with molecular oxygen at atmospheric pressure. Detailed study of the precursors preparation and reduction were undertaken. The catalyst 3%Pd-1%Bi where the bismuth was deposited on the palladium particles (3.4 nm) exhibited at 95% glycerol conversion more than 63% yield toward glyceric acid and tartronic acid after 3 h of reaction. The catalyst maintains practically similar catalytic performance as in fresh state for at least five consecutive catalytic cycles without extra catalyst treatment and reactivation. (C) 2016 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

引用

页码：77 / 86

页数：10

共 60 条

[1] "Microencapsulated" and Related Catalysts for Organic Chemistry and Organic Synthesis
Akiyama, Ryo
Kobayashi, Shu
[J]. CHEMICAL REVIEWS, 2009, 109 (02) : 594 - 642
[2] CATALYTIC-OXIDATION OF GLUCOSE ON BISMUTH-PROMOTED PALLADIUM CATALYSTS
BESSON, M
LAHMER, F
GALLEZOT, P
FUERTES, P
FLECHE, G
[J]. JOURNAL OF CATALYSIS, 1995, 152 (01) : 116 - 121
[3] Besson M., 2001, FINE CHEM HETEROGENE, P49
[4] Microgel-stabilized metal nanoclusters: Size control by microgel nanomorphology
Biffis, A
Orlandi, N
Corain, B
[J]. ADVANCED MATERIALS, 2003, 15 (18) : 1551 - +
[5] Microgel-stabilized gold nanoclusters: Powerful "quasi-homogeneous" catalysts for the aerobic oxidation of alcohols in water
Biffis, Andrea
Cunial, Sara
Spontoni, Paolo
Prati, Laura
[J]. JOURNAL OF CATALYSIS, 2007, 251 (01) : 1 - 6
[6] Generation of size-controlled palladium(0) and gold(0) nanoclusters inside the nanoporous domains of gel-type functional resins Part 11: Prospects for oxidation catalysis in the liquid phase
Burato, C
Centomo, P
Pace, G
Favaro, M
Prati, L
Corain, B
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 238 (1-2) : 26 - 34
[7] Bi-modified Pd/C catalyst via irreversible adsorption and its catalytic activity for ethanol oxidation in alkaline medium
Cai, Jindi
Huang, Yiyin
Guo, Yonglang
[J]. ELECTROCHIMICA ACTA, 2013, 99 : 22 - 29
[8] Oxidation of glycerol using supported Pt, Pd and Au catalysts
Carrettin, S
McMorn, P
Johnston, P
Griffin, K
Kiely, CJ
Hutchings, GJ
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (06) : 1329 - 1336
[9] Selective oxidation of alcohols and aldehydes over supported metal nanoparticles
Davis, Sara E.
Ide, Matthew S.
Davis, Robert J.
[J]. GREEN CHEMISTRY, 2013, 15 (01) : 17 - 45
[10] Oxidation of mono- and polyalcohols with gold: Comparison of carbon and ceria supported catalysts
Demirel, S.
Kern, P.
Lucas, M.
Claus, P.
[J]. CATALYSIS TODAY, 2007, 122 (3-4) : 292 - 300

← 1 2 3 4 5 6 →