Macrocyclic binuclear copper(II) and nickel(II) complexes: the key role of central ions in hydrogen peroxide electrocatalysis

被引：3
|
作者：
Roznyatovskaya, NV [1 ]
Tsirlina, GA [1 ]
Roznyatovskii, VV [1 ]
Mitiaev, AS [1 ]
Smurnyy, YD [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
来源：
MENDELEEV COMMUNICATIONS | 2005年 / 15卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1070/MC2005v015n03ABEH002100
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The electrochemistry of the macrocyclic dicopper(II) and dinickel(II) complexes [M2L]Cl-2, where L is the [2+2] condensation product of 1,3-diaminopropane and 2,6-diformyl-4-tert-butylphenol, is reported in relation to hydrogen peroxide electrocatalysis on mercury. The opposite effects observed with [Cu2L]Cl-2 (inhibition) and [Ni2L]Cl-2 (enhancement) are explained by different reduction mechanisms.
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页码：93 / 95
页数：3
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