''Half-sandwich'' YbIII single-ion magnets with metallacrowns

被引：86

作者：

Li, Quan-Wen ^{[1
]}

Liu, Jun-Liang ^{[1
]}

Jia, Jian-Hua ^{[1
]}

Chen, Yan-Cong ^{[1
]}

Liu, Jiang ^{[1
]}

Wang, Long-Fei ^{[1
]}

Tong, Ming-Liang ^{[1
]}

机构：

[1] Sun Yat Sen Univ, MOE Key Lab Bioinorgan & Synthet Chem, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 51期

关键词：

MOLECULE-MAGNET; LANTHANIDE COMPLEXES; MAGNETIZATION RELAXATION; ANISOTROPY BARRIER; YTTERBIUM; BEHAVIOR; LUMINESCENCE; BLOCKING; CLUSTER; FAMILY;

D O I：

10.1039/c5cc03389f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first ''half-sandwich'' Yb-III single-ion magnets (SIMs) based on [12-MCZn(II)-4] are reported, in which the central ytterbium ion is coordinated by YbO8 geometry in D-4d symmetry. The anisotropic barrier is extracted from the analysis of static, dynamic magnetism and emission spectrum offering an insight into the magneto-optical correlation.

引用

页码：10291 / 10294

页数：4

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