Synthesis and characterization of polymeric azido Zn(II) and Ni(II) complexes based on 3-hydroxypyridine

被引：6
作者：
Mautner, Franz A. [1 ]
Berger, Christian [1 ]
Domian, Elisabeth [1 ]
Fischer, Roland C. [2 ]
Massoud, Salah S. [3 ]
机构：
[1] Graz Univ Technol, Inst Phys & Theoret Chem, Stremayrgasse 9, A-8010 Graz, Austria
[2] Graz Univ Technol, Inst Anorgan Chem, Stremayrgasse 9, A-8010 Graz, Austria
[3] Univ Louisiana Lafayette, Dept Chem, POB 43700, Lafayette, LA 70504 USA
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2016年 / 1122卷
关键词：
Azide; Nickel; Zinc; 3-Hydroxypyridine; Crystal structure; Luminescence; DOUBLE END-ON; MAGNETIC-PROPERTIES; COORDINATION POLYMER; CRYSTAL-STRUCTURES; LUMINESCENCE PROPERTIES; CADMIUM(II) COMPLEXES; COPPER(II) COMPLEXES; MOLECULAR-STRUCTURE; THERMAL-STABILITY; X-RAY;
D O I：
10.1016/j.molstruc.2016.06.004
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The synthesis and structural characterization of two new complexes catena-[Ni(3-O-py)(3-HO-py)(2)(mu(1,3)-N-3)(H2O)] (1) and catena-[Zn(mu-3-O-py)(mu(1,1)-N-3)] (2), where 3-HO-py = 3-hydroxypyridine, are reported. The complexes were characterized by the elemental microanalyses, IR, and X-ray crystallography and by UV Vis spectroscopy for complex 1. Single crystal X-ray crystallography revealed the polymeric nature of the complexes: 1 as 1D with a single EE azide bridging, and 2 as 2D with mu(O,O',N) bridging of the deprotonated 3-O-py anions and di-EO azide groups, respectively. In 1 the neutral and deprotonated 3-hydroxypyridine molecules act only as N-terminal ligands. The emission spectral properties of the Zn(II) complex were investigated. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：234 / 238
页数：5
相关论文
共 65 条
  • [1] Abu-Youssef MAM, 2008, DALTON T, P3553, DOI 10.1039/b800022k
  • [2] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE
    ADDISON, AW
    RAO, TN
    REEDIJK, J
    VANRIJN, J
    VERSCHOOR, GC
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07): : 1349 - 1356
  • [3] Structural and magnetic studies on copper(II) azido complexes
    Adhikary, Chandan
    Koner, Subratanath
    [J]. COORDINATION CHEMISTRY REVIEWS, 2010, 254 (23-24) : 2933 - 2958
  • [4] Synthesis, structures and reactivity of N-donor-functionalised Cu(I) aryloxides
    Anson, CE
    Ponikiewski, L
    Rothenberger, A
    [J]. INORGANICA CHIMICA ACTA, 2006, 359 (07) : 2263 - 2267
  • [5] Crystal structures and magnetic behaviour of three new azido-bridged dinuclear cobalt(II) and copper(II) complexes
    Bai, SQ
    Gao, EQ
    He, Z
    Fang, CJ
    Yan, CH
    [J]. NEW JOURNAL OF CHEMISTRY, 2005, 29 (07) : 935 - 941
  • [6] Investigations of rotamers in diaxial Sn(IV)porphyrin phenolates - towards a molecular timepiece
    Bhosale, Sheshanath V.
    Chong, Connie
    Forsyth, Craig
    Langford, Steven J.
    Woodward, Clint R.
    [J]. TETRAHEDRON, 2008, 64 (36) : 8394 - 8401
  • [7] Copper-Azide-Thioarylazoimidazoles - Structure, Spectra, Redox Properties, Magnetism and Theoretical Interpretation
    Bhunia, Prasenjit
    Banerjee, Debasis
    Datta, Papia
    Raghavaiah, Pallepogu
    Slawin, Alexandra M. Z.
    Woollins, John D.
    Ribas, Joan
    Sinha, Chittaranjan
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (02) : 311 - 321
  • [8] Spin Canting and Metamagnetism in 2D and 3D Cobalt(II) Coordination Networks with Alternating Double End-On and Double End-to-End Azido Bridges
    Boonmak, Jaursup
    Nakano, Motohiro
    Chaichit, Narongsak
    Pakawatchai, Chaveng
    Youngme, Sujittra
    [J]. INORGANIC CHEMISTRY, 2011, 50 (15) : 7324 - 7333
  • [9] A new tetranuclear defective dicubane azide-bridged cobalt(II) complex
    Cano, Joan
    Mautner, Franz A.
    Berger, Christian
    Fischer, Roland C.
    Vicente, Ramon
    [J]. POLYHEDRON, 2013, 50 (01) : 240 - 245
  • [10] Synthesis, characterisation, crystal structures, and magnetic properties of one-dimensional oxalato-bridged metal(II) complexes with 3-hydroxypyridine and isoquinoline
    Castillo, O
    Luque, A
    Lloret, F
    Román, P
    [J]. INORGANICA CHIMICA ACTA, 2001, 324 (1-2) : 141 - 149
1234567