{2-[(Dimethylamino)methyl]phenyl}bis(4-methylphenyl)bismuthane

被引:9
作者
Kawahata, Masatoshi [2 ]
Yasuike, Shuji [1 ,3 ]
Kinebuchi, Izumi [1 ]
Yamaguchi, Kentaro [2 ]
Kurita, Jyoji [1 ]
机构
[1] Hokuriku Univ, Fac Pharmaceut Sci, Kanagawa, Kanazawa 9201181, Japan
[2] Tokushima Bunri Univ, Fac Pharmaceut Sci, Shido, Sanuki 7692193, Japan
[3] Hokuriku Univ, Org Frontier Res Prevent Pharmaceut Sci, Kanagawa, Kanazawa 9201181, Japan
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
X-RAY;
D O I
10.1107/S1600536810043655
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Bi(C(7)H(7))2(C(9)H(12)N)],was obtained by treating chlorodi(p-tolyl) bismuthane with o-lithio-N,N-dimethylbenzylamine. An intramolecular Bi center dot center dot center dot N nonbonding interaction is observed in the distorted trigonal triarylbismuth coordination of the title compound.
引用
收藏
页码:M25 / U371
页数:9
相关论文
共 12 条
[1]  
[Anonymous], 2005, APEX2 SAINT
[2]  
Farrugia L.J., 1997, J. Appl. Crystallogr., V30, P565, DOI [10.1107/S0021889897003117, DOI 10.1107/S0021889897003117]
[3]  
Farrugia L. J., 1999, Journal of Applied Crystallography, V32, P837, DOI [DOI 10.1107/S0021889812029111, 10.1107/S0021889899006020, DOI 10.1107/S0021889899006020]
[4]   ON ENANTIOMORPH-POLARITY ESTIMATION [J].
FLACK, HD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881
[5]  
Matano Y., 2001, ORGANOBISMUTH CHEM, P21
[6]   Synthesis of Sb-chiral organoantimony compounds having intramolecular Sb•••N interaction and their separation into optically pure compounds via ortho-palladated benzylamine complexes [J].
Okajima, S ;
Yasuike, S ;
Kakusawa, N ;
Osada, A ;
Yamaguchi, K ;
Seki, H ;
Kurita, J .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 656 (1-2) :234-242
[7]  
Sheldrick G.M., 1996, SADABS
[8]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122
[9]   Structural chemistry of bismuth compounds. I. Organobismuth derivatives [J].
Silvestru, C ;
Breunig, HJ ;
Althaus, H .
CHEMICAL REVIEWS, 1999, 99 (11) :3277-3327
[10]   CHIRAL CHLOROBISMUTHINES STABILIZED BY THE INTRAMOLECULAR COORDINATION OF AN N,N-DIMETHYLAMINO GROUP - X-RAY STRUCTURE-ANALYSIS, ASYMMETRIC INDUCTION AT THE BISMUTH CENTER, AND DYNAMIC BEHAVIOR IN SOLUTION [J].
SUZUKI, H ;
MURAFUJI, T ;
MATANO, Y ;
AZUMA, N .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1993, (23) :2969-2973