Polymer-modified supported palladium catalysts for the hydrogenation of acetylene compounds

被引：19
|
作者：
Zharmagambetova, A. K. [1 ]
Seitkalieva, K. S. [1 ]
Talgatov, E. T. [1 ]
Auezkhanova, A. S. [1 ]
Dzhardimalieva, G. I. [2 ]
Pomogailo, A. D. [2 ]
机构：
[1] Kazakh Acad Sci, DV Sokolskii Organ Catalysis & Electrochem Inst, Alma Ata 050010, Kazakhstan
[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia
来源：
KINETICS AND CATALYSIS | 2016年 / 57卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
catalysis; hydrogenation; acetylene compounds; polymer-modified catalysts;
D O I：
10.1134/S0023158416030174
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Palladium catalysts supported on zinc oxide modified with polyethylene glycol or pectin were synthesized and investigated in the hydrogenation of acetylene compounds. It was established that the polymercontaining catalysts reduce acetylene hyrbons to olefins with high activity, selectivity, and stability. The composition and structure of the obtained composites were studied by elemental analysis, transmission electron microscopy, and XPS spectroscopy. It was found that the nanosized particles of palladium uniformly immobilized on the surface of zinc oxide were formed in the course of the synthesis of a supported polymer/oxide complex.
引用
收藏
页码：360 / 367
页数：8
相关论文
共 50 条
  • [31] Supported palladium catalysts modified with heteropoly acids in 1,4-butynediol hydrogenation
    Zakarina, NA
    Volkova, LD
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2000, 73 (01) : 74 - 77
  • [32] HYDROGENATION OF ACETYLENE ON PALLADIUM
    PRADIER, CM
    MAZINA, M
    BERTHIER, Y
    OUDAR, J
    JOURNAL OF MOLECULAR CATALYSIS, 1994, 89 (1-2): : 211 - 220
  • [33] POLYMER-SUPPORTED ORGANOMETALLIC COMPOUNDS OF TITANIUM, ZIRCONIUM AND HAFNIUM AS HYDROGENATION CATALYSTS
    CHANDRASEKARAN, ES
    GRUBBS, RH
    BRUBAKER, CH
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 120 (01) : 49 - 63
  • [34] Polymer-supported catalysts for polymer hydrogenation.
    Wagner, NL
    Hillmyer, MA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U653 - U653
  • [35] Efficient Catalysts Based on Substitutional Solid Solutions and Palladium Intermetallic Compounds for the Selective Hydrogenation of Acetylene to Ethylene
    Shlyapin, D. A.
    Yurpalova, D. V.
    Afonasenko, T. N.
    Temerev, V. L.
    Lavrenov, A. V.
    CATALYSIS IN INDUSTRY, 2024, 16 (03) : 278 - 311
  • [36] Role of Interstitial Solid Solutions in the Formation of the Active Component of Supported Palladium Catalysts for the Selective Hydrogenation of Acetylene to Ethylene
    Shlyapin, D. A.
    Glyzdova, D. V.
    Afonasenko, T. N.
    Temerev, V. L.
    Lavrenov, A. V.
    CATALYSIS IN INDUSTRY, 2023, 15 (03) : 297 - 312
  • [37] HYDROGENATION OF UNSATURATED AND NITRO-COMPOUNDS ON POLYMER-SUPPORTED PALLADIUM(0) CHELATES
    UFLYAND, IE
    SHEINKER, VN
    BULATOV, AV
    POMOGAILO, AD
    JOURNAL OF MOLECULAR CATALYSIS, 1989, 55 (1-3): : 391 - 395
  • [38] Hydrogenation of olefins over palladium(II) complexes supported on a modified macroporous polymer bead
    Jo, YD
    Ahn, JH
    Ihm, SK
    POLYMER INTERNATIONAL, 1997, 44 (01) : 49 - 54
  • [39] HYDROGENATION OF ACETYLENE OVER SUPPORTED METAL-CATALYSTS .1. ADSORPTION OF [C-14]ACETYLENE AND [C-14]ETHYLENE ON SILICA SUPPORTED RHODIUM, IRIDIUM AND PALLADIUM AND ALUMINA SUPPORTED PALLADIUM
    ALAMMAR, AS
    WEBB, G
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1978, 74 : 195 - 205
  • [40] Role of Interstitial Solid Solutions in the Formation of the Active Component of Supported Palladium Catalysts for the Selective Hydrogenation of Acetylene to Ethylene
    D. A. Shlyapin
    D. V. Glyzdova
    T. N. Afonasenko
    V. L. Temerev
    A. V. Lavrenov
    Catalysis in Industry, 2023, 15 : 297 - 312
12345