The distribution and ecological risks of antibiotics in the sediments from a diverging area of the bifurcated river: Effects of hydrological properties

The hydrodynamics in the diverging area become complicated because of the basin hydrological conditions, making the distribution of antibiotics largely uncertain and thus bringing uncertain ecological risks of antibiotics. Through field sampling, experiments and numerical simulations, the distribution of antibiotics, its responses to hydrological conditions were studied. Antibiotics in the bifurcated river sediments was mainly distributed in the branch mouth. The hydrodynamic regions were affected by the hydrological frequency. Notably, the center of the low-velocity area moved upstream and gradually expands to the entire tributary as the hydrological frequency shifted from high to low. ENRO (enrofloxacin) and OFC (ofloxacin) were the key hazardous antibiotics affecting the ecological health in the diverging area, and their concentrations are mainly affected by sediment particle size (D < 0.15 mm) and oxygen content. The ecological risk of antibiotics in the diverging area were gradually decreased with the increase of the distance from the central area. The water physical and chemical properties, altered by the river basin hydrological conditions, play an important role in influencing the distribution of antibiotic concentrations, and ultimately posing great threat to aquatic ecosystem. The research provides a scientific basis for antibiotic risk control in the diverging area under different hydrological conditions.