Chiral separations in food analysis

被引:77
|
作者
D'Orazio, Giovanni [1 ]
Fanali, Chiara [2 ]
Asensio-Ramos, Maria [3 ]
Fanali, Salvatore [1 ]
机构
[1] Italian Natl Res Council CNR, Inst Chem Methodol, Monterotondo, Italy
[2] Campus Biomed Univ, Ctr Integrato Ric, Via Alvaro del Portillo 21, I-00128 Rome, Italy
[3] Inst Volcanol Canarias INVOLCAN, Parque Taoro, Tenerife, Spain
关键词
Analysis; Chiral; Enantiomers; Food; Gas chromatography; High-performance liquid chromatography; Nutraceutical; PERFORMANCE LIQUID-CHROMATOGRAPHY; SUPERCRITICAL-FLUID CHROMATOGRAPHY; MULTIDIMENSIONAL GAS-CHROMATOGRAPHY; TANDEM MASS-SPECTROMETRY; VOLATILE ORGANIC-COMPOUNDS; TUBULAR CAPILLARY ELECTROCHROMATOGRAPHY; MICELLAR ELECTROKINETIC CHROMATOGRAPHY; PARTIAL FILLING TECHNIQUE; CE RECENT DEVELOPMENTS; ALPHA-HYDROXY ACIDS;
D O I
10.1016/j.trac.2017.05.013
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The determination of enantiomers is a very important topic in different areas including pharmaceutical, biomedical, agrochemical and food fields. In fact these compounds possess quite similar physical-chemical characteristics and can exhibit different properties. Their separation can be obtained when the two enantiomers interact with a chiral environment. This is currently done in separation science employing analytical methods such as conventional or miniaturized liquid chromatography (LC), gas chromatography (GC), supercritical fluid chromatography (SFC), and electromigration techniques such as capillary electrophoresis (CE) and capillary electrochromatography (CEC). In this paper we overview the importance of analyzing enantiomers in food matrices and beverages. The selected applications include data available in literature in the period 2013-February 2017 and considering LC, GC, SFC, CE, CEC and capillary-LC. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:151 / 171
页数:21
相关论文
共 50 条
  • [41] Application of heparin to chiral separations of antihistamines by capillary electrophoresis
    Jin, YK
    Stalcup, AM
    ELECTROPHORESIS, 1998, 19 (12) : 2119 - 2123
  • [42] A comparison of chiral separations by supercritical fluid chromatography and high-performance liquid chromatography
    Ali, Imran
    Raja, Rupak
    Alam, Syed Dilshad
    Shirsath, Vikas
    K. Jain, Arvind
    Locatelli, Marcello
    David, Victor
    JOURNAL OF LIQUID CHROMATOGRAPHY & RELATED TECHNOLOGIES, 2021, 44 (11-12) : 550 - 563
  • [43] Amino Acid Ionic Liquids as Chiral Ligands in Ligand-Exchange Chiral Separations
    Liu, Qian
    Wu, Kangkang
    Tang, Fei
    Yao, Lihua
    Yang, Fei
    Nie, Zhou
    Yao, Shouzhuo
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (38) : 9889 - 9896
  • [44] Chiral and stable isotope analysis of synthetic cathinones
    Tai, Sherlock
    Morrison, Calum
    TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2017, 86 : 251 - 262
  • [45] Chiral Drug Analysis in Forensic Chemistry: An Overview
    Ribeiro, Claudia
    Santos, Cristiana
    Goncalves, Valter
    Ramos, Ana
    Afonso, Carlos
    Tiritan, Maria Elizabeth
    MOLECULES, 2018, 23 (02):
  • [46] Chiral capillary electrophoresis
    Bernardo-Bermejo, Samuel
    Sanchez-Lopez, Elena
    Castro-Puyana, Maria
    Luisa Marina, Maria
    TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2020, 124
  • [47] Authenticity Control of Food Flavorings - Merits and Limitations of Chiral Analysis
    Schaefer, Uwe
    Kiefl, Johannes
    Zhu, Wenqi
    Kempf, Michael
    Eggers, Marcus
    Backes, Michael
    Geissler, Torsten
    Wittlake, Radiger
    Reichelt, Katharina V.
    Ley, Jakob P.
    Krammer, Gerhard
    IMPORTANCE OF CHIRALITY TO FLAVOR COMPOUNDS, 2015, 1212 : 3 - 12
  • [48] Analysis of emerging contaminants in food
    Farre, Marinella
    Barcelo, Damia
    TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2013, 43 : 240 - 253
  • [49] Liquid chromatographic enantiomer separations applying chiral ion-exchangers based on Cinchona alkaloids
    Ilisz, Istvan
    Bajtai, Attila
    Lindner, Wolfgang
    Peter, Antal
    JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 2018, 159 : 127 - 152
  • [50] Productivity and solvent waste in supercritical fluid chromatography for preparative chiral separations: a guide for a convenient strategy
    Speybrouck, David
    Lipka, Emmanuelle
    JOURNAL OF CHROMATOGRAPHY A, 2020, 1610 (1610)