Chiral separations in food analysis

被引:77
|
作者
D'Orazio, Giovanni [1 ]
Fanali, Chiara [2 ]
Asensio-Ramos, Maria [3 ]
Fanali, Salvatore [1 ]
机构
[1] Italian Natl Res Council CNR, Inst Chem Methodol, Monterotondo, Italy
[2] Campus Biomed Univ, Ctr Integrato Ric, Via Alvaro del Portillo 21, I-00128 Rome, Italy
[3] Inst Volcanol Canarias INVOLCAN, Parque Taoro, Tenerife, Spain
关键词
Analysis; Chiral; Enantiomers; Food; Gas chromatography; High-performance liquid chromatography; Nutraceutical; PERFORMANCE LIQUID-CHROMATOGRAPHY; SUPERCRITICAL-FLUID CHROMATOGRAPHY; MULTIDIMENSIONAL GAS-CHROMATOGRAPHY; TANDEM MASS-SPECTROMETRY; VOLATILE ORGANIC-COMPOUNDS; TUBULAR CAPILLARY ELECTROCHROMATOGRAPHY; MICELLAR ELECTROKINETIC CHROMATOGRAPHY; PARTIAL FILLING TECHNIQUE; CE RECENT DEVELOPMENTS; ALPHA-HYDROXY ACIDS;
D O I
10.1016/j.trac.2017.05.013
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The determination of enantiomers is a very important topic in different areas including pharmaceutical, biomedical, agrochemical and food fields. In fact these compounds possess quite similar physical-chemical characteristics and can exhibit different properties. Their separation can be obtained when the two enantiomers interact with a chiral environment. This is currently done in separation science employing analytical methods such as conventional or miniaturized liquid chromatography (LC), gas chromatography (GC), supercritical fluid chromatography (SFC), and electromigration techniques such as capillary electrophoresis (CE) and capillary electrochromatography (CEC). In this paper we overview the importance of analyzing enantiomers in food matrices and beverages. The selected applications include data available in literature in the period 2013-February 2017 and considering LC, GC, SFC, CE, CEC and capillary-LC. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:151 / 171
页数:21
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