catena-Poly[[[aqua(formato-κO)(1,10-phenanthroline-κ2N,N′)manganese(II)]-μ-formato-κ2O:O′] monohydrate]

被引:1
作者
Xu, Wei [1 ]
机构
[1] Ningbo Univ, Ctr Appl Solid State Chem Res, Ningbo 315211, Zhejiang, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
MAGNETIC-PROPERTIES;
D O I
10.1107/S1600536811020575
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, {[Mn(HCOO)(2)(C12H8N2)(H2O)]center dot H2O}(n), consists of polymeric chains of the complex [Mn(HCOO)(2)(phen)(H2O)](infinity) (phen is 1,10-phenanthroline) with solvent water molecules. The chains contain six-coordinate Mn-II ions bridged by formate anions. They are further extended into a three-dimensional network via O-H center dot center dot center dot O hydrogen-bonding interactions and interchain pi-pi stacking interactions, with a centroid-centroid distance of 3.679 (4) angstrom.
引用
收藏
页码:M893 / U722
页数:11
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