Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex

被引：2

作者：

Cobeljic, Bozidar ^{[1
]}

Pevec, Andrej ^{[2
]}

Jaglicic, Zvonko ^{[3
,4
]}

Milenkovic, Milica R. ^{[1
]}

Turel, Iztok ^{[2
]}

Radanovic, Dusanka ^{[5
]}

Milenkovic, Marina ^{[6
]}

Andelkovic, Katarina ^{[1
]}

机构：

[1] Univ Belgrade, Fac Chem, Studentski Trg 12-16, Belgrade, Serbia

[2] Univ Ljubljana, Fac Chem & Chem Technol, Vecna Pot 113, Ljubljana 1000, Slovenia

[3] Univ Ljubljana, Inst Math Phys & Mech, Jadranska 19, Ljubljana, Slovenia

[4] Univ Ljubljana, Fac Civil & Geodet Engn, Jadranska 19, Ljubljana, Slovenia

[5] Univ Belgrade, Inst Chem Technol & Met, Njegoseva 12,POB 815, Belgrade 11000, Serbia

[6] Univ Belgrade, Dept Microbiol & Immunol, Fac Pharm, Vojvode Stepe 450, Belgrade 11221, Serbia

来源：

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY | 2018年 / 83卷 / 12期

关键词：

hydrazone; X-ray structure; magnetic properties; pseudohalides; METAL-COMPLEXES; CRYSTAL-STRUCTURES; ACYLHYDRAZONES; NI(II);

D O I：

10.2298/JSC180828079C

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The isothiocyanato Fe(III) complex with (E)-N, N, N-trimethyl-2-oxo- 2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs.

引用

页码：1327 / 1337

页数：11

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