Selective discrimination of closely related monosaccharides at physiological pH by a polymeric receptor

被引：31
作者：
Striegler, S [1 ]
机构：
[1] Univ Ulm, Div Inorgan Chem 2, D-89069 Ulm, Germany
来源：
TETRAHEDRON | 2001年 / 57卷 / 12期
关键词：
D O I：
10.1016/S0040-4020(01)00117-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
High selectivity for glucose by a polymeric receptor at physiological pH over other 1,2-cis-diols, namely mannose and galactose, and over a non-imprinted control polymer is reported. The shape selectivity of the imprinted cavity of the polymer has been examined in competing and non-competing rebinding experiments under saturation conditions applying weak binding interactions at physiological pH. The influence of the orientation of the functional groups during polymerisation resulting in the observed high shape selectivity of the cavity has been discussed. (C) 2001 Elsevier Science Ltd. All rights reserved.
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页码：2349 / 2354
页数：6
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