Synthesis and resolution of planar-chiral derivatives of 4-(Dimethylamino)pyridine

被引：36

作者：

Wurz, Ryan P. ^{[1
]}

Lee, Elaine C. ^{[1
]}

Ruble, J. Craig ^{[1
]}

Fu, Gregory C. ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2007年 / 349卷 / 14-15期

关键词：

asymmetric catalysis; asymmetric synthesis; heterocycles; homogeneous catalysis;

D O I：

10.1002/adsc.200700219

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A safer and more efficient method for the synthesis of planar-chiral 4-(dimethylamino)pyridine (DMAP) derivatives has been developed. Racemic mixtures of the complexes can be resolved via classical resolution with commercially available tartaric acids.

引用

收藏

页码：2345 / 2352

页数：8

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