High-resolution 14N solid-state NMR spectroscopy

被引：0

作者：

Jeschke, G ^{[1
]}

Jansen, M ^{[1
]}

机构：

[1] Univ Bonn, Inst Anorgan Chem, D-53121 Bonn, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1998年 / 37卷 / 09期

关键词：

nitrogen; NMR spectroscopy; solid-state structures;

D O I：

10.1002/(SICI)1521-3773(19980518)37:9<1282::AID-ANIE1282>3.0.CO;2-T

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Even without expensive isotope enrichment, it is possible to obtain nitrogen NMR parameters in the solid state. The isotropic chemical shifts in hexagonal and cubic boron nitride, and for the hexagonal modification also the quadrupole coupling, can thus be obtained for the first time. The recorded 14N MAS NMR spectrum (28.809 MHz) of hexagonal boron nitride is shown on the right.

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收藏

页码：1282 / 1283

页数：2

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