Hydrogenation of carboxylic acids catalyzed by magnesia-supported poly-γ-aminopropylsiloxane-Ru complex

被引：16

作者：

Mao, BW ^{[1
]}

Cai, ZZ ^{[1
]}

Huang, MY ^{[1
]}

Jiang, YY ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, 4060 Grp, Beijing 100080, Peoples R China

来源：

POLYMERS FOR ADVANCED TECHNOLOGIES | 2003年 / 14卷 / 3-5期

关键词：

catalytic hydrogenation; propionic acid; propyl alcohol; poly-gamma-aminopropylsiloxane; ruthenium complex;

D O I：

10.1002/pat.306

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Magnesia-supported poly-gamma-aminopropylsiloxane-ruthenium complex catalysts (MgO-NH2-Ru) have been prepared by a very simple method and have been found to be capable of catalyzing the hydrogenation of some simple carboxylic acids, such as acetic acid, propionic acid, lactic acid and isobutyric acid to give ethanol, propanol, 1,2-propanediol and isobutyl alcohol in 100% yields respectively in the presence of water at 240 degreesC and under 5.0 x 10(6) Pa H-2 for 18 h. The catalyst was very stable and could be used repeatedly without any noticeable changes in its catalytic activity. Copyright (C) 2003 John Wiley Sons, Ltd.

引用

页码：278 / 281

页数：4

共 5 条

[1] HYDROGENATION OF CARBOXYLIC-ACIDS USING BIMETALLIC CATALYSTS CONSISTING OF GROUP-8 TO GROUP-10, AND GROUP-6 OR GROUP-7 METALS [J].

HE, DH ;

WAKASA, N ;

FUCHIKAMI, T .

TETRAHEDRON LETTERS, 1995, 36 (07) :1059-1062

[2]

HUDLICKY M, 1985, REDUCTIONS ORGANIC C

[3]

MAO BW, IN PRESS POLYM ADV T

[4] HYDROFORMYLATION OF STYRENE TO 2-PHENYLPROPIONALDEHYDE CATALYZED BY SILICA-SUPPORTED POLY-GAMMA-AMINOPROPYLSILOXANE-RUTHENIUM-COBALT BIMETALLIC COMPLEX [J].

TANG, LM ;

HUANG, MY ;

JIANG, YY .

REACTIVE POLYMERS, 1994, 23 (2-3) :119-122

[5] HYDROGENATION OF ALDEHYDES AND KETONES CATALYZED BY PALLADIUM COMPLEXES OF SILICA-SUPPORTED POLY-GAMMA-CYANOPROPYLSILOXANE AND POLY-GAMMA-AMINOPROPYLSILOXANE [J].

ZHOU, YZ ;

JIANG, YY .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 251 (01) :31-37

← 1 →