Selective adsorption of arsenate and the reversible structure transformation of the mesoporous metal-organic framework MIL-100(Fe)

被引：115
作者：
Cai, Jianhua [1 ,2 ]
Wang, Xueyun [1 ,2 ]
Zhou, Yue [1 ,2 ]
Jiang, Li [1 ]
Wang, Chunru [1 ]
机构：
[1] Chinese Acad Sci, Inst Chem, Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2016年 / 18卷 / 16期
基金：
中国国家自然科学基金;
关键词：
ZERO-VALENT IRON; SURFACE-AREA; SORPTION; REMOVAL; PORES; ACID; POLYMERIZATION; ARSENIC(III); FERRIHYDRITE; CARBOXYLATE;
D O I：
10.1039/c6cp00249h
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Here we describe a highly porous metal-organic framework MIL-100(Fe), which is initially used as an arsenate adsorbent in water. An appropriate mesoporous size allows AsO43- to enter unrestrained and then be captured successfully, furthermore resulting in the damage of long-range order of uniform mesopores. Moreover, the porous framework could also make AsO43- be reversibly desorbed without structural changes and the long-range order of mesopores be recovered again.
引用
收藏
页码：10864 / 10867
页数：4
相关论文
共 31 条
[21]   Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units [J].
Rosi, NL ;
Kim, J ;
Eddaoudi, M ;
Chen, BL ;
O'Keeffe, M ;
Yaghi, OM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (05) :1504-1518
[22]   Large scale fluorine-free synthesis of hierarchically porous iron(III) trimesate MIL-100(Fe) with a zeolite MTN topology [J].
Seo, You-Kyong ;
Yoon, Ji Woong ;
Lee, Ji Sun ;
Lee, U-Hwang ;
Hwang, Young Kyu ;
Jun, Chul-Ho ;
Horcajada, Patricia ;
Serre, Christian ;
Chang, Jong-San .
MICROPOROUS AND MESOPOROUS MATERIALS, 2012, 157 :137-145
[23]   Very large breathing effect in the first nanoporous chromium(III)-based solids:: MIL-53 or CrIII(OH)•{O2C-C6H4-CO2}•{HO2C-C6H4-CO2H}x•H2Oy [J].
Serre, C ;
Millange, F ;
Thouvenot, C ;
Noguès, M ;
Marsolier, G ;
Louër, D ;
Férey, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (45) :13519-13526
[24]   Adsorption and polymerisation of silicic acid on ferrihydrite, and its effect on arsenic adsorption [J].
Swedlund, PJ ;
Webster, JG .
WATER RESEARCH, 1999, 33 (16) :3413-3422
[25]   Investigation of acid sites in a zeotypic giant pores chromium(III) carboxylate [J].
Vimont, A ;
Goupil, JM ;
Lavalley, JC ;
Daturi, M ;
Surblé, S ;
Serre, C ;
Millange, F ;
Férey, G ;
Audebrand, N .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (10) :3218-3227
[26]   A microdiffraction set-up for nanoporous metal-organic-framework-type solids [J].
Volkringer, Christophe ;
Popov, Dimitry ;
Loiseau, Thierry ;
Guillou, Nathalie ;
Ferey, Gerard ;
Haouas, Mohamed ;
Taulelle, Francis ;
Mellot-Draznieks, Caroline ;
Burghammer, Manfred ;
Riekel, Christian .
NATURE MATERIALS, 2007, 6 (10) :760-764
[27]   Synthesis, Single-Crystal X-ray Microdiffraction, and NMR Characterizations of the Giant Pore Metal-Organic Framework Aluminum Trimesate MIL-100 [J].
Volkringer, Christophe ;
Popov, Dimitry ;
Loiseau, Thierry ;
Ferey, Gerard ;
Burghammer, Manfred ;
Riekel, Christian ;
Haouas, Mohamed ;
Taulclle, Francis .
CHEMISTRY OF MATERIALS, 2009, 21 (24) :5695-5697
[28]   Arsenic mobility in the ambient sulfidic environment: Sorption of arsenic(V) and arsenic(III) onto disordered mackinawite [J].
Wolthers, M ;
Charlet, L ;
Van der Weijden, CH ;
Van der Linde, PR ;
Rickard, D .
GEOCHIMICA ET COSMOCHIMICA ACTA, 2005, 69 (14) :3483-3492
[29]   Iron(III) Modification of Bacillus subtilis Membranes Provides Record Sorption Capacity for Arsenic and Endows Unusual Selectivity for As(V) [J].
Yang, Ting ;
Chen, Ming-Li ;
Liu, Lan-Hua ;
Wang, Jian-Hua ;
Dasgupta, Purnendu K. .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2012, 46 (04) :2251-2256
[30]   Controlled Reducibility of a Metal-Organic Framework with Coordinatively Unsaturated Sites for Preferential Gas Sorption [J].
Yoon, Ji Woong ;
Seo, You-Kyong ;
Hwang, Young Kyu ;
Chang, Jong-San ;
Leclerc, Herve ;
Wuttke, Stefan ;
Bazin, Philippe ;
Vimont, Alexandre ;
Daturi, Marco ;
Bloch, Emily ;
Llewellyn, Philip L. ;
Serre, Christian ;
Horcajada, Patricia ;
Greneche, Jean-Marc ;
Rodrigues, Alirio E. ;
Ferey, Gerard .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (34) :5949-5952
1234