Synthesis and Properties of Star Polymers with a C5-Symmetric Bowl-Shaped Aromatic Core

被引：23

作者：

Stuparu, Mihaiela C. ^{[1
]}

机构：

[1] Univ Zurich, Inst Organ Chem, CH-8057 Zurich, Switzerland

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2012年 / 50卷 / 13期

基金：

瑞士国家科学基金会;

关键词：

corannulene; fullerenes; host-guest systems; polymer synthesis; star polymers; TRANSFER RADICAL POLYMERIZATION; MACROMOLECULAR ARCHITECTURES; CORANNULENE; DERIVATIVES; INITIATORS; COPOLYMERS; BLOCK; C-60;

D O I：

10.1002/pola.26038

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We report the synthesis and properties of star polymers with a C-5-symmetric aromatic core. For this, corannulene-based penta-substituted polymerization initiators were synthesized. These initiators were then used to polymerize cyclic ester and styrenic monomers via ring opening polymerization and free radical polymerization methods, respectively. Preliminary results suggest that these novel polymers can interact with fullerene, C-60, and the degree of interaction can be tuned by the chemical nature of the solvent. (C) 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 50: 26412649, 2012

引用

页码：2641 / 2649

页数：9

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