Ruthenium/magnesium-lanthanum mixed oxide: An efficient reusable catalyst for oxidation of alcohols by using molecular oxygen

被引：24

作者：

Kantam, M. Lakshmi ^{[1
]}

Reddy, R. Sudarshan ^{[1
]}

Pal, Ujjwal ^{[1
]}

Sudhakar, M. ^{[1
]}

Venugopal, A. ^{[1
]}

Ratnam, K. Jeeva ^{[1
]}

Figueras, F. ^{[2
]}

Chintareddy, Venkat Reddy ^{[3
]}

Nishina, Yuta ^{[4
]}

机构：

[1] Indian Inst Chem Technol, Inorgan & Phys Chem Div, Hyderabad 500607, Andhra Pradesh, India

[2] Inst Rech Catalyse & Environm, F-69626 Villeurbanne, France

[3] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

[4] Okayama Univ, Res Core Interdisciplinary Sci, Kita Ku, Tsushima, Okayama 7008530, Japan

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2012年 / 359卷

关键词：

Oxidation; Alcohols; Ru/Mg-LaO mixed oxide; Heterogeneous; Solvent free; AEROBIC OXIDATION; SELECTIVE OXIDATION; HETEROGENEOUS OXIDATION; RUTHENIUM CATALYST; METAL-OXIDE; HYDROXYAPATITE; ALDEHYDES; PERRUTHENATE; HYDROTALCITE; CONVERSIONS;

D O I：

10.1016/j.molcata.2012.03.013

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An efficient method for the oxidation of benzylic and secondary aromatic alcohols into their corresponding aldehydes or ketones has been achieved by using ruthenium supported magnesium lanthanum mixed oxide as a heterogeneous catalyst in toluene, with molecular oxygen as the sole oxidant. This catalyst can also be operated in solvent free conditions at 393 K and reused for five cycles with consistent yield and selectivity. (C)2012 Elsevier B.V. All rights reserved.

引用

页码：1 / 7

页数：7

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