Orthorhombic to tetragonal phase transition due to stress release in (Li,Ta)-doped(K,Na)NbO3 lead-free piezoceramics

被引：58

作者：

Zhou, Jia-Jun ^{[1
]}

Li, Jing-Feng ^{[1
]}

Zhang, Xiao-Wen ^{[1
]}

机构：

[1] Tsinghua Univ, State Key Lab New Ceram & Fine Proc, Dept Mat Sci & Engn, Beijing 100084, Peoples R China

来源：

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 2012年 / 32卷 / 02期

关键词：

Piezoelectric properties; Niobates; Perovskites; PIEZOELECTRIC PROPERTIES; CERAMICS;

D O I：

10.1016/j.jeurceramsoc.2011.09.001

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

XRD and Raman scattering experiments revealed an interesting finding that phase structure changed from orthorhombic to tetragonal symmetry when pulverizing (Li,Ta)-doped (K,Na)NbO3 lead-free piezoelectric ceramics (sintered body) to powder. Both orthorhombic and tetragonal phases coexist in the Li-0.05(Na0.51K0.49)(0.95)Nb0.80Ta0.20O3.00 (LKNNT) sintered bulk sample at room temperature, but almost only the tetragonal phase is observed in the ground powder. In addition, annealing experiment enhanced the formation of tetragonal phase and improved the temperature stability of piezoelectricity. It is revealed that the internal stress existing in the LKNNT ceramics favors the formation of orthorhombic phase, which transfers to tetragonal phase when the stress was released. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：267 / 270

页数：4

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