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Density, Viscosity, and Surface Tension of Liquid Phase Beckmann Rearrangement Mixtures
被引:2
作者
:
Zuidhof, Klaas T.
论文数:
0
引用数:
0
h-index:
0
机构:
Eindhoven Univ Technol, Lab Chem Reactor Engn, Dept Chem Engn & Chem, NL-5600 MB Eindhoven, Netherlands
Eindhoven Univ Technol, Lab Chem Reactor Engn, Dept Chem Engn & Chem, NL-5600 MB Eindhoven, Netherlands
Zuidhof, Klaas T.
[
1
]
de Croon, Mart H. J. M.
论文数:
0
引用数:
0
h-index:
0
机构:
Eindhoven Univ Technol, Lab Chem Reactor Engn, Dept Chem Engn & Chem, NL-5600 MB Eindhoven, Netherlands
Eindhoven Univ Technol, Lab Chem Reactor Engn, Dept Chem Engn & Chem, NL-5600 MB Eindhoven, Netherlands
de Croon, Mart H. J. M.
[
1
]
Schouten, Jaap C.
论文数:
0
引用数:
0
h-index:
0
机构:
Eindhoven Univ Technol, Lab Chem Reactor Engn, Dept Chem Engn & Chem, NL-5600 MB Eindhoven, Netherlands
Eindhoven Univ Technol, Lab Chem Reactor Engn, Dept Chem Engn & Chem, NL-5600 MB Eindhoven, Netherlands
Schouten, Jaap C.
[
1
]
Tinge, Johan T.
论文数:
0
引用数:
0
h-index:
0
机构:
DSM Chem Technol R&D BV, Ind Chem, NL-6160 MD Geleen, Netherlands
Eindhoven Univ Technol, Lab Chem Reactor Engn, Dept Chem Engn & Chem, NL-5600 MB Eindhoven, Netherlands
Tinge, Johan T.
[
2
]
机构
:
[1]
Eindhoven Univ Technol, Lab Chem Reactor Engn, Dept Chem Engn & Chem, NL-5600 MB Eindhoven, Netherlands
[2]
DSM Chem Technol R&D BV, Ind Chem, NL-6160 MD Geleen, Netherlands
来源
:
JOURNAL OF CHEMICAL AND ENGINEERING DATA
|
2015年
/ 60卷
/ 04期
关键词
:
20-DEGREES-C;
D O I
:
10.1021/je500836b
中图分类号
:
O414.1 [热力学];
学科分类号
:
摘要
:
We have determined the density, dynamic viscosity, and surface tension of liquid phase Beckmann rearrangement mixtures, consisting of ε-caprolactam and fuming oleum. These important properties have been measured in wide ranges of both temperature and molar ratios of acid and ε-caprolactam, covering conditions that are of relevance for industrial production of ε-caprolactam from cyclohexanone oxime, i.e., T = (293 to 393) K and ([H2SO4] + [SO3])/[ε-caprolactam] = (1.4 to 2.6). The results were correlated as functions of temperature and composition. The density of oleum/ε-caprolactam mixtures shows a linear relationship with both temperature and composition. A modification of the traditional Reynolds model proved to be the most suitable way to represent the dynamic viscosity of these Beckmann rearrangement mixtures. The reduction of the surface tension with temperature is described with a power law expression, while the decrease of the surface tension with increasing molar ratios of acid over ε-caprolactam is described with a linear relationship. These results can be applied to design liquid phase Beckmann rearrangement processes on both large scale and microscale. (Graph Presented). © 2015 American Chemical Society.
引用
收藏
页码:1056 / 1062
页数:7
相关论文
共 23 条
[21]
Beckmann Rearrangement of Cyclohexanone Oxime in a Microreactor Setup with Internal Recirculation
[J].
Zuidhof, Niek T.
论文数:
0
引用数:
0
h-index:
0
机构:
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Zuidhof, Niek T.
;
de Croon, Mart H. J. M.
论文数:
0
引用数:
0
h-index:
0
机构:
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
de Croon, Mart H. J. M.
;
Schouten, Jaap C.
论文数:
0
引用数:
0
h-index:
0
机构:
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Schouten, Jaap C.
;
Tinge, Johan T.
论文数:
0
引用数:
0
h-index:
0
机构:
R&D BV Ind Chem, DSM Chem Technol, Geleen, Netherlands
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Tinge, Johan T.
.
CHEMICAL ENGINEERING & TECHNOLOGY,
2013,
36
(08)
:1387
-1394
[22]
Beckmann Rearrangement of Cyclohexanone Oxime to ε-Caprolactam in a Microreactor
[J].
Zuidhof, Niek T.
论文数:
0
引用数:
0
h-index:
0
机构:
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Zuidhof, Niek T.
;
de Croon, Mart H. J. M.
论文数:
0
引用数:
0
h-index:
0
机构:
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
de Croon, Mart H. J. M.
;
Schouten, Jaap C.
论文数:
0
引用数:
0
h-index:
0
机构:
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Schouten, Jaap C.
;
Tinge, Johan T.
论文数:
0
引用数:
0
h-index:
0
机构:
DSM Chem Technol R&D BV Ind Chem, Geleen, Netherlands
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Tinge, Johan T.
.
CHEMICAL ENGINEERING & TECHNOLOGY,
2012,
35
(07)
:1257
-1261
[23]
1951, Patent No. 2573374
←
1
2
3
→
共 23 条
[21]
Beckmann Rearrangement of Cyclohexanone Oxime in a Microreactor Setup with Internal Recirculation
[J].
Zuidhof, Niek T.
论文数:
0
引用数:
0
h-index:
0
机构:
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Zuidhof, Niek T.
;
de Croon, Mart H. J. M.
论文数:
0
引用数:
0
h-index:
0
机构:
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
de Croon, Mart H. J. M.
;
Schouten, Jaap C.
论文数:
0
引用数:
0
h-index:
0
机构:
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Schouten, Jaap C.
;
Tinge, Johan T.
论文数:
0
引用数:
0
h-index:
0
机构:
R&D BV Ind Chem, DSM Chem Technol, Geleen, Netherlands
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Tinge, Johan T.
.
CHEMICAL ENGINEERING & TECHNOLOGY,
2013,
36
(08)
:1387
-1394
[22]
Beckmann Rearrangement of Cyclohexanone Oxime to ε-Caprolactam in a Microreactor
[J].
Zuidhof, Niek T.
论文数:
0
引用数:
0
h-index:
0
机构:
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Zuidhof, Niek T.
;
de Croon, Mart H. J. M.
论文数:
0
引用数:
0
h-index:
0
机构:
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
de Croon, Mart H. J. M.
;
Schouten, Jaap C.
论文数:
0
引用数:
0
h-index:
0
机构:
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Schouten, Jaap C.
;
Tinge, Johan T.
论文数:
0
引用数:
0
h-index:
0
机构:
DSM Chem Technol R&D BV Ind Chem, Geleen, Netherlands
Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
Tinge, Johan T.
.
CHEMICAL ENGINEERING & TECHNOLOGY,
2012,
35
(07)
:1257
-1261
[23]
1951, Patent No. 2573374
←
1
2
3
→