Radical reactions on pinene-oxide derivatives induced by Ti(III)

被引：18
作者：
Fernandez-Mateos, A. [1 ]
Herrero Teijon, P. [1 ]
Rubio Gonzalez, R. [1 ]
机构：
[1] Univ Salamanca, Fac Ciencias Quim, Dept Quim Organ, E-37008 Salamanca, Spain
来源：
TETRAHEDRON | 2011年 / 67卷 / 49期
关键词：
Pinene-derived terpenoids; Titanocene; Radical reactions; alpha-Pinene oxide; Epoxides; ALPHA-PINENE; ELECTRON-TRANSFER; SELENIUM DIOXIDE; NATURAL-PRODUCTS; EPOXIDES; ISOMERIZATION; REARRANGEMENT; OXIDATION; TERPENES; CONVERSION;
D O I：
10.1016/j.tet.2011.10.004
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A practical, brief and selective synthesis of several pinene oxide derived terpenoids can be achieved from readily available starting materials. The key step is a radical reaction promoted by titanocene chloride. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：9529 / 9534
页数：6
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