Syntheses and characterization of two new 4,4′-bithiazole d10 complexes, structural characterization of M(DABTZ)2(CH3COO](ClO4) • 2H2O (M = Zn, Cd)

被引：0
作者：
Abedini, J
Morsali, A
机构：
[1] Tarbiat Modares Univ, Sch Sci, Dept Chem, Tehran, Iran
[2] Peyame Noor Univ, Abhar Ctr, Dept Chem, Abhar Zanjan, Iran
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2005年 / 60卷 / 09期
关键词：
zinc; cadmium; crystal structure; 2,2 '-diamino-4,4 '-bithiazole;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New zinc(II) and cadmium(II) complexes of the 2,2'-diamino-4,4'-bithiazole (DABTZ) ligand, [M(DABTZ)(2)(CH3COO)](ClO4), have been synthesized and characterized by elemental analysis, IR, H-1 NMR and C-13 NMR spectroscopy. The structural characterization of the Cd(DABTZ)(2)(CH3COO)](ClO4) center dot 2H(2)O complex shows the complex to be a monomer and the Cd atom to be coordinated by four nitrogen atoms of the "DABTZ" ligands and two oxygen atoms of the acetate anion. There is an edge-to-edge pi-pi stacking interaction between the parallel aromatic rings.
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页码：951 / 954
页数：4
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