Stereochemical control of cis- and trans-TiCl2 groups in six-coordinate complexes [(L)TiCl2] (L2- = N2O2-donor Schiff base) and reactions with trimethylaluminium to form cationic aluminium species

被引：80
作者：
Corden, JP [1 ]
Errington, W [1 ]
Moore, P [1 ]
Wallbridge, MGH [1 ]
机构：
[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
来源：
CHEMICAL COMMUNICATIONS | 1999年 / 04期
关键词：
D O I：
10.1039/a808372j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first example of a cis-configuration of the TiCl2 group in a six-coordinate titanium complex [(L)TiCl2], involving a tetradentate N2O2-donor Schiff base ligand (L2-), is reported, and reactions of such complexes with trimethyl aluminium have been shown to generate cationic aluminium species.
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页码：323 / 324
页数：2
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