Transport properties of ion-exchange membranes during pervaporation of water-alcohol mixtures

被引:12
|
作者
Kujawski, W
Pozniak, G
机构
[1] Nicholas Copernicus Univ, Fac Chem, PL-87100 Torun, Poland
[2] Wroclaw Univ Technol, Inst Organ & Polymer Technol, Wroclaw, Poland
关键词
pervaporation; PESS ion-exchange membrane; Nafion; 117; membrane; water-aliphatic alcohol mixtures;
D O I
10.1080/01496390500201458
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pervaporation properties of PESS ion-exchange membranes in contact with water-aliphatic alcohol mixtures were obtained. PESS ion-exchange membranes were prepared by chemical modification of the interpenetrating polymer network system polyethylene-poly(styrene-co-divinylbenzene). PESS membranes were loaded with different alkali metal ions as counterions. The obtained data showed that properties of PESS membranes depended strongly on the kind of counterions, degree of cross-linking, and difference in the polarities between water and organic component of the binary mixture. Results obtained for PESS membranes were compared with data obtained for Nation 117 ion-exchange membrane.
引用
收藏
页码:2277 / 2295
页数:19
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