Palladium phosphanyl-β-ketoiminate complexes as highly active catalysts for Heck coupling reaction

被引：4
|
作者：
Lee, Dong-Hwan [1 ]
Cho, Min-Ho [1 ]
Kwon, Ik-Hyun [1 ]
Jun, In-Chul [2 ]
Lee, Ik-Mo [1 ]
Jin, Myung-Jong [1 ]
机构：
[1] Inha Univ, Dept Chem Engn & Chem, Inchon 402751, South Korea
[2] JaiNeung Coll, Dept Cosmet, Inchon 401714, South Korea
来源：
CATALYSIS COMMUNICATIONS | 2008年 / 9卷 / 06期
关键词：
Heck reaction; phosphanyl-beta-ketoimine; Pd complex; catalysis;
D O I：
10.1016/j.catcom.2008.01.004
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Phosphanyl-beta-ketoiminate complexes of palladium were conveniently prepared from 2,4-pentanedione and primary amines ill two-pot three steps. These Pd complexes acted as highly active catalysts for Heck coupling reaction of aryl iodides and bromides with acrylates. The catalyst system was also effective for the coupling of aryl chlorides. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：1517 / 1520
页数：4
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