Homochiral Zn and Cd coordination polymers containing amino acid-tetrazole ligands

被引：139
作者：
Qu, ZR
Zhao, H
Wang, XS
Li, YH
Song, YM
Liu, YJ
Ye, QO
Xiong, RG
Abrahams, BF
Xue, ZL
You, XZ
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Univ Melbourne, Sch Chem, Parkville, Vic 3052, Australia
[3] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
来源：
INORGANIC CHEMISTRY | 2003年 / 42卷 / 24期
关键词：
HUISGEN 1,3-DIPOLAR CYCLOADDITION; CLICK CHEMISTRY APPROACH; 5-SUBSTITUTED; 1H-TETRAZOLES; STEREOSELECTIVE-SYNTHESIS; BONDING MODE; METAL; COMPLEXES; SOLIDS; MOLECULES; DESIGN;
D O I：
10.1021/ic034685q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of (S)-3-cyanophenylalanine with NaN3 in the presence of H2O and Lewis acids (ZnCl2 and CdCl2) afford two unprecedented 3D homochiral networks, mono[(S)-5-(3-tetrazoyl)-phenylalaninato]zinc(II) (1) and mono[(S)-5-(3-tetrazoyl)-phenylalaninato]cadmium(II) monoaqua(II) (2), respectively. The two compounds are isostructural with noninterpenetrated SrAl2 topology. The structure of these coordination polymers gives new insight into Sharpless' reaction of chiral 5-substituted 1H-tetrazole and homochiral supramolecular array constructions.
引用
收藏
页码：7710 / 7712
页数：3
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