Homochiral Zn and Cd coordination polymers containing amino acid-tetrazole ligands

被引：139

作者：

Qu, ZR

Zhao, H

Wang, XS

Li, YH

Song, YM

Liu, YJ

Ye, QO

Xiong, RG

Abrahams, BF

Xue, ZL

You, XZ

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Univ Melbourne, Sch Chem, Parkville, Vic 3052, Australia

[3] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 24期

关键词：

HUISGEN 1,3-DIPOLAR CYCLOADDITION; CLICK CHEMISTRY APPROACH; 5-SUBSTITUTED; 1H-TETRAZOLES; STEREOSELECTIVE-SYNTHESIS; BONDING MODE; METAL; COMPLEXES; SOLIDS; MOLECULES; DESIGN;

D O I：

10.1021/ic034685q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of (S)-3-cyanophenylalanine with NaN3 in the presence of H2O and Lewis acids (ZnCl2 and CdCl2) afford two unprecedented 3D homochiral networks, mono[(S)-5-(3-tetrazoyl)-phenylalaninato]zinc(II) (1) and mono[(S)-5-(3-tetrazoyl)-phenylalaninato]cadmium(II) monoaqua(II) (2), respectively. The two compounds are isostructural with noninterpenetrated SrAl2 topology. The structure of these coordination polymers gives new insight into Sharpless' reaction of chiral 5-substituted 1H-tetrazole and homochiral supramolecular array constructions.

引用

页码：7710 / 7712

页数：3

共 66 条

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