A pillared-bilayer porous coordination polymer with a 1D channel and a 2D interlayer space, showing unique gas and vapor sorption

被引：98
作者：
Kanoo, Prakash [2 ]
Mostafa, Golam [3 ]
Matsuda, Ryotaro [1 ,4 ]
Kitagawa, Susumu [1 ,4 ,5 ]
Maji, Tapas Kumar [2 ]
机构：
[1] JST, ERATO, Kitagawa Integrated Pore Project, Shimogyo Ku, Kyoto 6008815, Japan
[2] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India
[3] Jadavpur Univ, Dept Phys, Kolkata 700032, India
[4] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Sakyo Ku, Kyoto 6158510, Japan
[5] Kyoto Univ, Dept Synthet Chem & Biol Chem, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 28期
关键词：
METAL-ORGANIC FRAMEWORK; GUEST ADSORPTION; ANION-EXCHANGE; CRYSTAL; SEPARATION; CATALYSIS; BEHAVIOR; LIGANDS; COMPLEX; METHANE;
D O I：
10.1039/c1cc11416f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new 2D pillared-bilayer porous coordination polymer (PCP) has been synthesized and structurally characterized that shows selective adsorption of CO2 over other gases (N-2, O-2, Ar, H-2, CH4) and guest selective single/double-step adsorption of vapor correlated to the successive confinement of adsorbates in a 1D channel and a 2D interlayer space.
引用
收藏
页码：8106 / 8108
页数：3
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