Dichlorido(9-methyladenine-κN7)(η5-pentamethylcyclopentadienyl)-iridium(III) dichloromethane solvate

被引：4
|
作者：
Bruhn, Clemens [2 ]
Kueger, Thomas [1 ]
Steinborn, Dirk [1 ]
机构：
[1] Univ Halle Wittenberg, Inst Chem Anorgan Chem, D-06120 Halle, Germany
[2] Univ Kassel, Naturwissenschaften, Abt Metallorgan Chem, FB 18, D-34132 Kassel, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808003760
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, [Ir(C10H15)Cl-2(C6H7N5)]center dot CH2Cl2 or [Ir(eta(5)-C5Me5)Cl-2(9-MeAde-kappa N-7)]center dot CH2Cl2 (9-MeAde = 9-methyladenine), the coordination geometry of the Ir-III atom approximates to a three-legged piano stool. The 9-methyladenine ligand is coordinated in a monodentate fashion to the Ir centre through its N-7 atom. The crystal structure contains centrosymmetric pairs of molecules, interacting through two N-H center dot center dot center dot N hydrogen bonds. An intramolecular N - H center dot center dot center dot Cl hydrogen bond is formed between the H atom of an NH2 group and a chlorido ligand. Further short intra- and intermolecular C - H center dot center dot center dot Cl contacts are observed.
引用
收藏
页码：M455 / U207
页数：12
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