A 3D hydrogen bonding framework of trinuclear Ni(II) complex in mixed ligands system: Structural and magnetic studies

被引：10
作者：
Chen, Xiao-hua [1 ]
Wu, Qiong-jie [2 ]
Lu, Wei [1 ]
Yang, Ming-xing [1 ]
Chen, Li-juan [1 ]
机构：
[1] Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China
[2] Fujian Agr & Forestry Univ, Coll Life Sci, Fuzhou 350002, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 05期
关键词：
Linear trinuclear Nickel(II) complex; Mixed ligands; Hydrogen bonding; 3D framework; Magnetism; TRIDENTATE SCHIFF-BASE; CRYSTAL-STRUCTURE; NICKEL(II) COMPLEXES; COPPER(II); BIOACTIVITY;
D O I：
10.1016/j.inoche.2011.02.008
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Employing N-benzoyl-salicylhydrazide (H(3)bzshz) and imidazole (Himdz) as mixed ligands, a novel linear trinuclear Ni(II) complex [Ni-3(bzshz)(2)(Himdz)(2)(H2O)(2)]center dot 2DMF (1) has been synthesized and characterized. The three nickel atoms in 1 arrange in a strictly linear structure. The complex exhibits a novel 3D hydrogen bonding framework through the intermolecular O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonding interactions. The magnetic property of 1 has been investigated by variable temperature magnetic susceptibility measurement. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：694 / 696
页数：3
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