A carbon-free polyoxometalate molecular catalyst with a cobalt-arsenic core for visible light-driven water oxidation

被引：37

作者：

Chen, Wei-Chao ^{[1
]}

Wang, Xin-Long ^{[1
]}

Qin, Chao ^{[1
]}

Shao, Kui-Zhan ^{[1
]}

Su, Zhong-Min ^{[1
]}

Wang, En-Bo ^{[1
]}

机构：

[1] Northeast Normal Univ, Dept Chem, Inst Funct Mat Chem, Key Lab Polyoxometalate Sci,Minist Educ, Changchun 130024, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 61期

关键词：

CLUSTERS;

D O I：

10.1039/c6cc03763a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A carbon-free, stable, homogeneous water oxidation catalyst based on the unique hepta-nuclear cobalt-arsenic core ("fused" double-quasi-cubane) and polyoxometalate ligands, Na-12[{(Co7As6O9)-As-II-O-III(OH)(6)}-(A-alpha-SiW9O34)(2)]center dot 8H(2)O (1), was synthesized, thoroughly characterized and employed to catalyze water oxidation under visible-light-driven conditions.

引用

收藏

页码：9514 / 9517

页数：4

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