1-(4-Bromophenyl)-3-butanoylthiourea

被引：1

作者：

Saeed, Sohail ^{[1
]}

Rashid, Naghmana ^{[1
]}

Jasinski, Jerry P. ^{[2
]}

Butcher, Ray J. ^{[3
]}

Shoaib, Muhammad ^{[4
]}

机构：

[1] Allama Iqbal Open Univ, Dept Chem, Islamabad, Pakistan

[2] Keene State Coll, Dept Chem, Keene, NH 03435 USA

[3] Howard Univ, Dept Chem, Washington, DC 20059 USA

[4] Natl Engn & Sci Commiss, Islamabad, Pakistan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

D O I：

10.1107/S1600536810050373

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C11H13BrN2OS, there are two independent molecules (A and B) in the asymmetric unit. The dihedral angle between the mean planes of the benzene ring and the carbamothioyl group is 63.66 (molecule A) and 80.3 (0)degrees (molecule B). The butanamide group in molecule A is disordered [0.532 (6) and 0.468 (6) occupancy]. The carbamothioyl group is twisted by 63.6 (6) (molecule A) and 80.3 (0)degrees (molecule B) from the respective benzene ring. A strong intramolecular N-H center dot center dot center dot O hydrogen bond occurs in each molecule. The crystal packing is stabilized by weak intermolecular N-H center dot center dot center dot O and N-H center dot center dot center dot S hydrogen-bond interactions, the latter forming an infinite co-operative hydrogen-bonded two-dimensional network along [110].

引用

页码：O46 / U1702

页数：13

共 50 条

[21] 1-(4-Bromophenyl)-3-(4-methoxyphenyl)prop-2-en-1-one
Shettigar, Venkataraya
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
Razak, Ibrahim Abdul
Patil, P. S.
Dharmaprakash, S. M.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O4128 - O4129
[22] 3-(4-BROMOPHENYL)-1-(3-THIENYL)-2-PROPEN-1-ONE (BTC)
HE, YP
WU, QG
SU, GB
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1995, 51 : 1167 - 1168
[23] [3-(4-bromophenyl)-1-(4-methoxphenyl)pyrazol-5-yl]acetonitrile
Malhotra, S
Parmar, VS
Errington, W
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 1885 - 1887
[24] 1-(4-Bromophenyl)-2-(2-propenylsulfonyl)ethanone
Young, DJ
King, MD
Healy, PC
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O1668 - O1669
[25] 1-(4-Bromophenyl)-2-(2-chlorophenoxy)ethanone
Shenvi, Seema S.
Isloor, Arun M.
Gerber, Thomas
Hosten, Eric
Betz, Richard
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O3478 - +
[26] (E)-N′-[1-(4-Bromophenyl)ethylidene]-2-hydroxybenzohydrazide
Fan, Chuan-Gang
Song, Ming-Zhi
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2792 - U1173
[27] 3-(4-Bromophenyl)-1-(3-thienyl)-2-propen-1-one (BTC)
1600, Munksgaard Int Publ. Ltd., Copenhagen K, Denmark (51):
[28] 1-(4-bromophenyl)-3-(3-hydroxyphenyl)prop-2-en-1-one
Moorthi, SS
Chinnakali, K
Nanjundan, S
Unnithan, CS
Fun, HK
Yu, XL
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O483 - O485
[29] 2-[1-(4-Bromophenyl)-3-hydroxy-3-(4-methoxyphenyl)propyl]cyclohexanol
Celik, Ismail
Akkurt, Mehmet
Gezegen, Hayreddin
Uremis, Muhammed M.
Duteanu, Narcis
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O1091 - +
[30] [3-(4-Bromophenyl)-1-(4-methoxyphenyl) -pyrazol-5-yl]acetonitrile
Univ of Delhi, Delhi, India
Acta Crystallogr Sect C Cryst Struct Commun, pt 12 (1885-1887):

← 1 2 3 4 5 →