Two fluorescence turn-on chemosensors based on pyrrolo[2,1-a] isoquinoline for detection of Ag+ in aqueous solution

被引:26
作者
Jiang, Yuliang [1 ]
Kong, Weiwei [1 ]
Shen, Yongmiao [2 ]
Wang, Bingxiang [1 ]
机构
[1] Nanjing Normal Univ, Sch Chem & Mat Sci, Nanjing 210097, Jiangsu, Peoples R China
[2] Shaoxing Univ, Chem & Chem Engn, Shaoxing 312000, Peoples R China
基金
中国国家自然科学基金;
关键词
Pyrrolo[2,1-a]isoquinoline; Fluorescent; Turn-on; Limits of detection; 1,3-DIPOLAR CYCLOADDITION; HG2+; YLIDES; AG(I); WATER; IONS;
D O I
10.1016/j.tet.2015.06.055
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In this study, two water-soluble fluorescent probes based on pyrrolo[2,1-a]isoquinoline derivatives (4a and 4b) were synthesized and characterized by IR, H-1 NMR, C-13 NMR, MS spectra and elemental analysis for the first time. The obtained compounds (4a and 4b) showed fluorescent 'turn-on' phenomenon to Ag+ with limits of detection (LOD) of 0.6 mu M (4a) and 0.8 mu M (4b) (S/N=3), respectively. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5584 / 5588
页数:5
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