Efficient and direct synthesis of saccharidic 1,2-ethylidenes, orthoesters, and glycals from peracetylated sugars via the in situ generation of glycosyl iodides with I2/Et3SiH

被引：52

作者：

Adinolfi, M ^{[1
]}

Iadonisi, A ^{[1
]}

Ravidà, A ^{[1
]}

Schiattarella, M ^{[1
]}

机构：

[1] Univ Naples Federico II, Dipartimento Chim Organ & Biochim, I-80126 Naples, Italy

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 43期

关键词：

glycosyl iodides; orthoesters; glycals; ethylidenes;

D O I：

10.1016/j.tetlet.2003.09.022

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Peracetylated sugars can be efficiently converted into the corresponding 1,2-ethylidenes, -orthoesters, and -glycals via the in situ generation of glycosyl iodides promoted by I-2/Et3SiH. The approach is straightforward and avoids isolation of the sensitive iodinated intermediates. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：7863 / 7866

页数：4

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