Co-sensitization promoted light harvesting for plastic dye-sensitized solar cells

被引：61

作者：

Lee, Kun-Mu ^{[2
]}

Hsu, Ying-Chan ^{[3
]}

Ikegami, Masashi ^{[4
]}

Miyasaka, Tsutomu ^{[4
]}

Thomas, K. R. Justin ^{[5
,6
]}

Lin, Jiann T. ^{[3
]}

Ho, Kuo-Chuan ^{[1
]}

机构：

[1] Natl Taiwan Univ, Dept Chem Engn, Taipei 10617, Taiwan

[2] Ind Technol Res Inst, Green Energy & Environm Res Labs, Hsinchu 31040, Taiwan

[3] Acad Sinica, Inst Chem, Taipei 11529, Taiwan

[4] Toin Univ Yokohama, Grad Sch Engn, Kanagawa 2258502, Japan

[5] Indian Inst Technol, Dept Chem, Roorkee 247667, Uttar Pradesh, India

[6] Indian Inst Technol, Ctr Nanotechnol, Roorkee 247667, Uttar Pradesh, India

来源：

JOURNAL OF POWER SOURCES | 2011年 / 196卷 / 04期

关键词：

Co-sensitization; Dye-sensitized solar cell; Photoelectrochemistry; Plastic solar cell; LOW-TEMPERATURE FABRICATION; NANOCRYSTALLINE TIO2 FILMS; ELECTRODES; COSENSITIZATION; PHOTOELECTRODES; EFFICIENCY; CYANINE;

D O I：

10.1016/j.jpowsour.2010.10.041

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A stepwise co-sensitization of a TiO2 mesoporous film in conjunction with two dye molecules using different sequences of adsorption for achieving a complementary spectral characteristic is investigated for application to a low-temperature fabrication plastic dye-sensitized solar cell (plastic DSSCs) The stepwise co-sensitization by monomolecular adsorption of N719/FL and black dye/FL show enhanced photovoltaic performances for the pertinent plastic DSSCs compare with that of the cell with the corresponding individual dyes The optimal conversion efficiencies of plastic DSSCs with N719/FL and black dye/FL are found to be 5 10% and 3 78% respectively which are higher than those of the cells with the corresponding individual sensitizers The incident photon-to-current conversion efficiency (IPCE) and electrochemical impedance spectroscopy (EIS) are also used to analysis these behaviors (C) 2010 Elsevier B V All rights reserved

引用

页码：2416 / 2421

页数：6

共 26 条

[1]

[Anonymous], 2008, Angew. Chemistry

[2]

[Anonymous], 2006, ANGEW CHEM

[3]

Bisquert J, 2002, J PHYS CHEM B, V106, P325, DOI 10.1021/jp01194lg

[4] Determination of rate constants for charge transfer and the distribution of semiconductor and electrolyte electronic energy levels in dye-sensitized solar cells by open-circuit photovoltage decay method [J].

Bisquert, J ;

Zaban, A ;

Greenshtein, M ;

Mora-Seró, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (41) :13550-13559

[5] Optimization of dye-sensitized solar cells prepared by compression method [J].

Boschloo, G ;

Lindström, J ;

Magnusson, E ;

Holmberg, A ;

Hagfeldt, A .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 148 (1-3) :11-15

[6] Highly efficient co-sensitization of nanocrystalline TiO2 electrodes with plural organic dyes [J].

Chen, YS ;

Zeng, ZH ;

Li, C ;

Wang, WB ;

Wang, XS ;

Zhang, BW .

NEW JOURNAL OF CHEMISTRY, 2005, 29 (06) :773-776

[7] Stepwise Cosensitization of Nanocrystalline TiO2 Films Utilizing Al2O3 Layers in Dye-Sensitized Solar Cells [J].

Choi, Hyunbong ;

Kim, Sanghoon ;

Kang, Sang Ook ;

Ko, Jaejung ;

Kang, Moon-Sung ;

Clifford, John N. ;

Forneli, Amparo ;

Palomares, Emilio ;

Nazeeruddin, Mohammad K. ;

Graetzel, Michael .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (43) :8259-8263

[8] Molecular cosensitization for efficient panchromatic dye-sensitized solar cells [J].

Cid, Juan-Jose ;

Yum, Jun-Ho ;

Jang, Song-Rim ;

Nazeeruddin, Mohammad K. ;

Ferrero, Eugenia Martinez ;

Palomares, Emilio ;

Ko, Jaejung ;

Graetzel, Michael ;

Torres, Tomas .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (44) :8358-8362

[9] Multistep electron transfer processes on dye co-sensitized nanocrystalline TiO2 films [J].

Clifford, JN ;

Palomares, E ;

Nazeeruddin, K ;

Thampi, R ;

Grätzel, M ;

Durrant, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (18) :5670-5671

[10] Spectral sensitization of TiO2 nanocrystalline electrodes with aggregated cyanine dyes [J].

Ehret, A ;

Stuhl, L ;

Spitler, MT .

JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (41) :9960-9965

← 1 2 3 →