Oxidative degradation of reducing carbohydrates to ammonium formate with H2O2 and NH4OH

被引：16
|
作者：
Pullanikat, Prasanna
Jung, Sangmook J.
Yoo, Kyung Soo
Jung, Kyung Woon [1 ]
机构：
[1] Univ So Calif, Loker Hydrocarbon Res Inst, Los Angeles, CA 90089 USA
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 47期
关键词：
ALKALINE HYDROGEN-PEROXIDE; ACID FUEL-CELLS; CARBON BOND-CLEAVAGE; FORMIC-ACID; HYDROPEROXIDES; 1,2-DIOLS; IRON; CATALYSTS; MECHANISM; SUGARS;
D O I：
10.1016/j.tetlet.2010.09.092
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Oxidation of various carbohydrates into ammonium formate was investigated in the presence of hydrogen peroxide and ammonium hydroxide. Most of the examined carbohydrates except nonreducing sugars were efficiently converted into ammonium formate under environment friendly and mild conditions in aqueous media. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6192 / 6194
页数：3
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