Crystalline phases and YAG laser-induced crystallization in SM2O3-Bi2O3-B2O3 glasses

被引：21

作者：

Honma, T

Benino, Y

Fujiwara, T

Komatsu, T ^{[1
]}

Sato, R

机构：

[1] Nagaoka Univ Technol, Dept Chem, Nagaoka, Niigata 9402188, Japan

[2] Tsuruoka Natl Coll Technol, Dept Mat Engn, Tsuruoka 9978511, Japan

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2005年 / 88卷 / 04期

关键词：

D O I：

10.1111/j.1551-2916.2005.00166.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The glass formation region, crystalline phases, second harmonic (SH) generation, and Nd:yttrium aluminum garnet (YAG) laser-induced crystallization in the Sm2O3-Bi2O3-B2O3 system were clarified. The crystalline phases of Bi4B2O9, Bi3B5O12, BiBO3, SmxBi1-xBO3, and SmB3O6 were formed through the usual crystallization in an electric furnace. The crystallized glasses consisting of BiBO3 and SmxBi1-xBO3 showed SH generations. The formation of the nonlinear optical BiB3O6 phase was not confirmed. The formation (writing) region of crystal fines consisting of SmxBi1-xBO3 by YAG laser irradiation was determined, in which Sm2O3 contents were similar to 10 mol%. The present study demonstrates that Sm2O3-M2O3-B2O3 glasses are promising materials for optical functional applications.

引用

页码：989 / 992

页数：4

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